Thorium
Thorium is a soft, silvery, mildly radioactive metal, and one of the most abundant radioactive elements in Earth's crust — considerably more plentiful than uranium. It's been used historically for the bright glow it gives certain materials when heated, and it's drawn renewed interest in recent years as a potential alternative fuel for nuclear power.
- Group · Period
- — · 7
- At room temp
- solid
- Melts at
- 2023 K
- Density
- 11.72 g/cm³
- Discovered
- 1828
Uses
Thorium’s most historically visible use was in gas lantern mantles, where thorium dioxide’s ability to glow brilliantly white when heated made it the standard choice for camping and household gas lighting for much of the 20th century; that use has largely disappeared as thorium-free mantles became standard, partly over radiation concerns. Thorium compounds were also once used in high-quality camera and telescope lenses because they bend light in useful optical ways, another application that has mostly been replaced by non-radioactive glass formulations.
The area generating the most current interest is nuclear energy: thorium can be converted inside a reactor into a fissile form of uranium, offering a potential alternative nuclear fuel cycle that some researchers believe could be safer and less wasteful than conventional uranium fuel, and that could make use of more abundant thorium reserves in countries like India. Thorium-based reactors remain largely in the research and development stage rather than widespread commercial use.
History
Thorium was discovered in 1828 by Swedish chemist Jöns Jacob Berzelius, who identified it in a mineral sample sent to him from Norway. He named the new element thorium after Thor, the Norse god of thunder, continuing a pattern of mythological naming common in that era of chemistry. Its radioactivity wasn’t recognized until decades later, once the broader phenomenon of radioactivity was discovered in the late 19th century, after which thorium became an important subject of study in the emerging field of nuclear science.
Fun facts
- Thorium is estimated to be several times more abundant in Earth's crust than uranium, making it one of the more common radioactive elements.
- Thorium is named after Thor, the Norse god of thunder, chosen by its discoverer to reflect its powerful, striking properties.
- Old camping lantern mantles once used thorium compounds because thorium dioxide glows with a brilliant white light when heated in a flame — a use now discontinued due to radiation concerns.
Frequently asked questions
Why were old lantern mantles radioactive?
Thorium dioxide has a very high melting point and glows with an unusually bright white light when heated by a flame, which made it ideal for gas lantern mantles for many decades. Because the amount of thorium involved was small and mostly emits radiation that doesn't travel far, the risk was considered low, though manufacturers have since largely switched to non-radioactive alternatives.
Could thorium replace uranium as a nuclear fuel?
It's a real and active area of research. Thorium itself isn't directly fissile, but it can be converted inside a reactor into a form of uranium that is, offering a potential nuclear fuel cycle that some researchers argue could produce less long-lived waste and draw on more abundant reserves. Several countries are exploring the idea, but thorium-based reactors are not yet in widespread commercial use.
Who discovered thorium?
Swedish chemist Jöns Jacob Berzelius discovered thorium in 1828 while analyzing a mineral sample, and he named the new element after Thor, the Norse god of thunder. Berzelius was one of the most prolific element discoverers of his era, and his careful analytical methods set a standard for chemistry that lasted long after his death.
Compounds
4 notable compounds containing Th
- ThO2oxide
Thorium dioxide
Known as thoria, a white refractory solid with the highest melting point of any known oxide, which once made it prized for emitting a bright white glow when heated in gas lamp mantles.
Used for: Historic incandescent gas-lantern mantles and high-temperature ceramics
- Th(NO3)4salt
Thorium nitrate
A water-soluble crystalline salt once produced on an industrial scale because fabric soaked in its solution, then ignited, left behind a fragile mesh of thorium dioxide that glowed brilliantly in gas lamps.
Used for: Historic impregnating agent for gas-lantern mantles
- ThCl4salt
Thorium tetrachloride
A white, strongly hygroscopic solid that fumes on contact with moist air, serving as a common laboratory starting point for making other thorium compounds.
Used for: Laboratory precursor for synthesizing other thorium compounds
- ThF4salt
Thorium tetrafluoride
A white, high-melting solid that serves as the key intermediate between thorium ore concentrates and metallic thorium, produced by reducing it with calcium metal.
Used for: Intermediate in the production of thorium metal
Isotopes
32 known isotopes
Swipe to see all columns →
| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Th-230 | 0.02% | 7.54E+4 Y | Alpha decay (100%), 24NE (5.8e-11%), Spontaneous fission (4e-12%) | 30,862.51 keV | 7,631 keV | 1.92 × 10-28 eV |
| Th-232 | 99.98% | 1.40E10 Y | Alpha decay (100%), Spontaneous fission (1.1e-9%) | 35,446.71 keV | 7,615.03 keV | 1.03 × 10-33 eV |
Show all 32 isotopes
| Th-207 | — | 10 ms | Alpha decay (100%) | — | — | 4.56 × 10-14 eV |
| Th-208 | — | 1.7 ms | Alpha decay (100%) | 16,688.04 keV | 7,652.57 keV | 2.68 × 10-13 eV |
| Th-209 | — | 2.5 ms | Alpha decay (100%) | 16,395 keV | 7,656 keV | 1.82 × 10-13 eV |
| Th-210 | — | 16 ms | Alpha decay (100%), Electron capture / beta-plus decay | 14,059.52 keV | 7,669.08 keV | 2.85 × 10-14 eV |
| Th-211 | — | 37 ms | Alpha decay, Electron capture / beta-plus decay | 13,876.4 keV | 7,671.85 keV | 1.23 × 10-14 eV |
| Th-212 | — | 31.7 ms | Alpha decay (100%) | 12,110.89 keV | 7,682.06 keV | 1.44 × 10-14 eV |
| Th-213 | — | 146 ms | Alpha decay (100%) | 12,120.11 keV | 7,683.85 keV | 3.12 × 10-15 eV |
| Th-214 | — | 87 ms | Alpha decay (100%) | 10,694.93 keV | 7,692.32 keV | 5.24 × 10-15 eV |
| Th-215 | — | 1.2 s | Alpha decay (100%) | 10,921.43 keV | 7,693.03 keV | 3.80 × 10-16 eV |
| Th-216 | — | 26.0 ms | Alpha decay (100%), Electron capture / beta-plus decay (0.01%) | 10,298.54 keV | 7,697.66 keV | 1.75 × 10-14 eV |
| Th-217 | — | 0.252 ms | Alpha decay (100%) | 12,205.78 keV | 7,690.59 keV | 1.81 × 10-12 eV |
| Th-218 | — | 122 ns | Alpha decay (100%) | 12,366.75 keV | 7,691.6 keV | 3.74 × 10-9 eV |
| Th-219 | — | 1.025 us | Alpha decay (100%) | 14,462.78 keV | 7,683.77 keV | 4.45 × 10-10 eV |
| Th-220 | — | 9.7 us | Alpha decay (100%), Electron capture (2e-7%) | 14,689.54 keV | 7,684.5 keV | 4.70 × 10-11 eV |
| Th-221 | — | 1.74 ms | Alpha decay (100%) | 16,939.93 keV | 7,676.06 keV | 2.62 × 10-13 eV |
| Th-222 | — | 2.24 ms | Alpha decay (100%) | 17,203.04 keV | 7,676.66 keV | 2.04 × 10-13 eV |
| Th-223 | — | 0.60 s | Alpha decay (100%) | 19,385.4 keV | 7,668.64 keV | 7.60 × 10-16 eV |
| Th-224 | — | 1.04 s | Alpha decay (100%) | 19,995.58 keV | 7,667.72 keV | 4.39 × 10-16 eV |
| Th-225 | — | 8.75 m | Alpha decay (90%), Electron capture (10%) | 22,310.19 keV | 7,659.22 keV | 8.69 × 10-19 eV |
| Th-226 | — | 30.57 m | Alpha decay (100%) | 23,197.65 keV | 7,657.12 keV | 2.49 × 10-19 eV |
| Th-227 | — | 18.697 d | Alpha decay (100%) | 25,804.76 keV | 7,647.46 keV | 2.82 × 10-22 eV |
| Th-228 | — | 1.9116 Y | Alpha decay (100%) | 26,770.9 keV | 7,645.08 keV | 7.56 × 10-24 eV |
| Th-229 | — | 7880 Y | Alpha decay (100%) | 29,585.52 keV | 7,634.65 keV | 1.83 × 10-27 eV |
| Th-231 | — | 25.57 h | Beta-minus decay (100%) | 33,815.81 keV | 7,620.12 keV | 4.96 × 10-21 eV |
| Th-233 | — | 21.83 m | Beta-minus decay (100%) | 38,731.64 keV | 7,602.89 keV | 3.48 × 10-19 eV |
| Th-234 | — | 24.10 d | Beta-minus decay (100%) | 40,612.96 keV | 7,596.86 keV | 2.19 × 10-22 eV |
| Th-235 | — | 7.2 m | Beta-minus decay (100%) | 44,017.75 keV | 7,584.39 keV | 1.06 × 10-18 eV |
| Th-236 | — | 37.5 m | Beta-minus decay (100%) | 46,255.2 keV | 7,576.97 keV | 2.03 × 10-19 eV |
| Th-237 | — | 4.8 m | Beta-minus decay (100%) | 49,955.1 keV | 7,563.44 keV | 1.58 × 10-18 eV |
| Th-238 | — | 9.4 m | Beta-minus decay (100%) | 52,525 keV | 7,555 keV | 8.09 × 10-19 eV |