91Pa231.03588
Actinide

Protactinium

Protactinium is a rare, dense, highly radioactive metal that sits between thorium and uranium on the periodic table, and one of the least accessible elements to study, since even the small amounts extracted from uranium ore are difficult and hazardous to purify. Its name reflects its place in the decay chain: it decays into actinium, so it was named using the Greek prefix for "before."

Group · Period
— · 7
At room temp
solid
Melts at
1845 K
Density
15.37 g/cm³
Discovered
1913

Uses

Protactinium has virtually no industrial or commercial applications, since it’s exceedingly rare, difficult to extract safely, and intensely radioactive. Its main relevance is scientific: researchers use it in nuclear physics studies to better understand radioactive decay processes within the actinide series. One genuinely useful application comes from geology and oceanography, where scientists measure the ratio of protactinium-231 to thorium-230 isotopes preserved in layers of deep ocean sediment, a technique that helps date those sediment layers and study how ocean circulation patterns have shifted over thousands of years.

History

Protactinium was first identified in 1913 by chemists Kasimir Fajans and Oswald Helmuth Göhring, who detected a short-lived radioactive isotope of the element and named it “brevium” because of how quickly it decayed away. Several years later, other researchers, including Otto Hahn and Lise Meitner, identified a much longer-lived isotope of the same element, which could be studied far more practically, and the element was renamed protactinium — reflecting that it decays into actinium, so it precedes actinium in the radioactive decay chain. Because it’s so rare and difficult to isolate, protactinium remained one of the least-studied naturally occurring elements for much of the 20th century.

Fun facts

  • Protactinium's name comes from the Greek word protos, meaning 'first' or 'before,' because it decays into actinium — so it comes before actinium in the decay chain.
  • Protactinium is extraordinarily rare — extracting even a small sample requires processing large quantities of uranium ore, since it occurs only as a fleeting trace within it.
  • One of protactinium's few practical roles is in geology, where the ratio of protactinium to thorium isotopes in ocean sediment helps scientists date sediment layers and study past ocean circulation.

Frequently asked questions

Why is protactinium so hard to study?

Protactinium is both extremely rare in nature and intensely radioactive, so isolating even a small amount requires processing large quantities of uranium ore under carefully controlled conditions. Because of this, only very limited quantities of pure protactinium have ever been separated and studied.

Does protactinium have any real use?

It has essentially no industrial or commercial use, but it plays a genuine role in scientific research. Geologists and oceanographers use the ratio between protactinium and thorium isotopes found in seafloor sediment to help date those sediment layers and reconstruct how ocean currents behaved thousands of years in the past.

Why did protactinium have two different discovery stories?

In 1913, chemists Kasimir Fajans and Oswald Helmuth Göhring found a short-lived isotope of the element and called it "brevium," a name reflecting how quickly it decayed. It was a different, much longer-lived isotope, identified years later by other researchers, that made the element easier to study and led to it being renamed protactinium.

Compounds

2 notable compounds containing Pa

  • PaCl5salt

    Protactinium pentachloride

    A pale yellow solid built from chains of chlorine-bridged protactinium atoms, notable for subliming readily under vacuum rather than melting cleanly.

    Used for: Precursor used in the reduction of protactinium to its metallic form

  • Pa2O5oxide

    Protactinium pentoxide

    A white solid and the most stable, best-studied protactinium compound, formed by igniting protactinium salts in air and used as the reference point for calculating the element's atomic weight.

    Used for: Reference compound in protactinium research; precursor to protactinium metal

Isotopes

29 known isotopes

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IsotopeNatural abundanceHalf-lifeDecay modeMass excessBinding energy / nucleonDecay width
Pa-231 100% 32570 Y Alpha decay (100%), Spontaneous fission (3e-10%) 33,424.34 keV 7,618.43 keV 4.44 × 10-28 eV
Show all 29 isotopes
Pa-211 300 ns Alpha decay, Electron capture / beta-plus decay, Proton emission 22,052.23 keV 7,629.39 keV 1.52 × 10-9 eV
Pa-212 5.1 ms Alpha decay (100%) 21,596.52 keV 7,633.63 keV 8.95 × 10-14 eV
Pa-213 5.3 ms Alpha decay (100%) 19,654.19 keV 7,644.8 keV 8.61 × 10-14 eV
Pa-214 17 ms Alpha decay (100%) 19,459.9 keV 7,647.7 keV 2.68 × 10-14 eV
Pa-215 14 ms Alpha decay (100%) 17,804.54 keV 7,657.37 keV 3.26 × 10-14 eV
Pa-216 0.15 s Alpha decay (98%), Electron capture (2%) 17,823.8 keV 7,659.2 keV 3.04 × 10-15 eV
Pa-217 3.8 ms Alpha decay (100%) 17,054.75 keV 7,664.64 keV 1.20 × 10-13 eV
Pa-218 109 us Alpha decay (100%) 18,649.57 keV 7,659.19 keV 4.19 × 10-12 eV
Pa-219 54 ns Alpha decay (100%) 18,583.22 keV 7,661.38 keV 8.45 × 10-9 eV
Pa-220 0.78 us Alpha decay (100%), Electron capture / beta-plus decay (3e-7%) 20,278.4 keV 7,655.54 keV 5.85 × 10-10 eV
Pa-221 5.9 us Alpha decay (100%) 20,374.94 keV 7,656.98 keV 7.73 × 10-11 eV
Pa-222 2.9 ms Alpha decay (100%) 22,064.36 keV 7,651.24 keV 1.57 × 10-13 eV
Pa-223 5.1 ms Alpha decay (100%) 22,337.61 keV 7,651.9 keV 8.95 × 10-14 eV
Pa-224 0.846 s Alpha decay (100%) 23,862.35 keV 7,646.96 keV 5.39 × 10-16 eV
Pa-225 1.7 s Alpha decay (100%) 24,356.64 keV 7,646.65 keV 2.68 × 10-16 eV
Pa-226 1.8 m Alpha decay (74%), Electron capture / beta-plus decay (26%) 26,033.6 keV 7,641.11 keV 4.22 × 10-18 eV
Pa-227 38.3 m Alpha decay (85%), Electron capture (15%) 26,830.37 keV 7,639.49 keV 1.99 × 10-19 eV
Pa-228 22 h Electron capture / beta-plus decay (98.15%), Alpha decay (1.85%) 28,923.6 keV 7,632.21 keV 5.76 × 10-21 eV
Pa-229 1.50 d Electron capture (99.52%), Alpha decay (0.48%) 29,896.85 keV 7,629.88 keV 3.52 × 10-21 eV
Pa-230 17.4 d Electron capture / beta-plus decay (92.2%), Beta-minus decay (7.8%), Alpha decay (0.0032%) 32,173.54 keV 7,621.9 keV 3.03 × 10-22 eV
Pa-232 1.32 d Beta-minus decay (100%), Electron capture 35,946.55 keV 7,609.51 keV 4.00 × 10-21 eV
Pa-233 26.975 d Beta-minus decay (100%) 37,489.41 keV 7,604.87 keV 1.96 × 10-22 eV
Pa-234 6.70 h Beta-minus decay (100%) 40,338.87 keV 7,594.68 keV 1.89 × 10-20 eV
Pa-235 24.4 m Beta-minus decay (100%) 42,288.9 keV 7,588.41 keV 3.12 × 10-19 eV
Pa-236 9.1 m Beta-minus decay (100%) 45,333.96 keV 7,577.56 keV 8.36 × 10-19 eV
Pa-237 8.7 m Beta-minus decay (100%) 47,527.62 keV 7,570.38 keV 8.74 × 10-19 eV
Pa-238 2.28 m Beta-minus decay (100%) 50,894.04 keV 7,558.34 keV 3.34 × 10-18 eV
Pa-239 1.8 h Beta-minus decay (100%) 53,337 keV 7,550 keV 7.04 × 10-20 eV