Selenium
Selenium is a grayish nonmetal that sits directly below sulfur on the periodic table and shares some of its chemistry, but with a distinctive talent all its own: its electrical conductivity changes dramatically when light shines on it. It's also one of the few elements that's both essential to human health in trace amounts and toxic in excess.
- Group · Period
- 16 · 4
- At room temp
- solid
- Melts at
- 493.65 K
- Density
- 4.809 g/cm³
- Discovered
- 1817
Uses
Selenium’s photoconductivity — its ability to conduct electricity much more readily when exposed to light — made it central to the technology behind early photocopiers and light-sensitive exposure meters, where a selenium-coated surface converts patterns of light into an electrical signal. It’s also used to decolorize glass by counteracting the greenish tint that iron impurities naturally give it, and, in higher concentrations, to produce a deep ruby-red glass and certain ceramic glazes.
In nutrition, selenium is an essential trace mineral that the body uses in antioxidant enzymes and thyroid-related processes, which is why small amounts appear in multivitamins and are naturally present in foods like Brazil nuts, seafood and grains. Selenium compounds are also used in some anti-dandruff shampoos and in agriculture as a soil supplement in regions where local soils are naturally deficient in it.
History
Selenium was discovered in 1817 by Swedish chemists Jöns Jacob Berzelius and Johan Gottlieb Gahn while they were investigating reddish sediment left behind during sulfuric acid production. Berzelius initially suspected the material was tellurium, an element discovered decades earlier, but careful analysis showed it was something new that simply behaved similarly. Because tellurium had been named after the Earth, using the Latin word tellus, Berzelius named the new element selenium after Selene, the Greek goddess of the moon, treating the pairing as a kind of chemical companionship between the two elements.
Fun facts
- Selenium was named after Selene, the Greek goddess of the moon, because it was found alongside tellurium, which had already been named after the Earth.
- Its conductivity increases sharply when exposed to light, a property called photoconductivity that made it central to early photocopiers and light meters.
- Selenium is an essential trace nutrient for humans, but the gap between a healthy dose and a toxic one is unusually narrow for an element.
Frequently asked questions
Is selenium good for you or dangerous?
Both, depending on the amount. Selenium is an essential trace element that the body needs in small quantities for antioxidant enzymes and thyroid function, which is why it appears in multivitamins and some foods naturally. But because the useful dose range is narrow, consuming too much — through supplements or contaminated food or water — can cause selenium toxicity.
Why is selenium named after the moon?
Its discoverers, Jöns Jacob Berzelius and Johan Gottlieb Gahn, found selenium in 1817 in residue left over from sulfuric acid production, mixed in with tellurium, an element already named after the Earth via the Latin word tellus. Naming the new, closely related element after the moon, via the Greek word selene, continued that theme.
What was selenium's role in old photocopiers and cameras?
Selenium is photoconductive, meaning it barely conducts electricity in the dark but conducts much more readily when light hits it. Older photocopiers and light meters exploited this to translate patterns of light and shadow into an electrical signal or a static charge that could be developed into an image.
Compounds
4 notable compounds containing Se
- H2Segas
Hydrogen selenide
A colorless, extremely toxic gas with a foul odor reminiscent of rotten radishes, the selenium analog of hydrogen sulfide and a byproduct of some metal refining processes.
Used for: Dopant source gas in semiconductor and solar-cell manufacturing
- SeO2oxide
Selenium dioxide
A white to pale yellow solid and the most common laboratory selenium compound, readily formed by burning selenium in air and dissolving in water to give selenous acid.
Used for: Oxidizing agent in organic synthesis and catalyst for selective allylic oxidation
- H2SeO3acid
Selenous acid
A weak, water-soluble acid formed when selenium dioxide dissolves in water, serving as the parent compound for selenite salts.
Used for: Precursor for selenite compounds and a bluing agent in gun-metal finishing
- Na2SeO3salt
Sodium selenite
A white crystalline salt that is the most common source of dietary selenium supplementation, dissolving readily to deliver selenium in a bioavailable form.
Used for: Selenium supplement in animal feed and multivitamins
Isotopes
33 known isotopes
Swipe to see all columns →
| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Se-74 stable | 0.86% | Stable | — | -72,213.21 keV | 8,687.72 keV | — |
| Se-76 stable | 9.23% | Stable | — | -75,251.96 keV | 8,711.48 keV | — |
| Se-77 stable | 7.6% | Stable | — | -74,599.5 keV | 8,694.69 keV | — |
| Se-78 stable | 23.69% | Stable | — | -77,025.95 keV | 8,717.81 keV | — |
| Se-80 stable | 49.8% | Stable | — | -77,759.49 keV | 8,710.81 keV | — |
| Se-82 | 8.82% | 9.6E+19 Y | Double beta-minus decay (100%) | -77,593.9 keV | 8,693.2 keV | 1.51 × 10-43 eV |
Show all 33 isotopes
| Se-63 | — | 13.2 ms | Electron capture / beta-plus decay (100%), ECP (89%), Two-proton emission (0.5%) | -16,850 keV | 7,917 keV | 3.46 × 10-14 eV |
| Se-64 | — | — | Electron capture / beta-plus decay (100%), ECP | -26,860 keV | 8,075 keV | — |
| Se-65 | — | 33 ms | Electron capture / beta-plus decay (100%), ECP (100%) | -33,020 keV | 8,170 keV | 1.38 × 10-14 eV |
| Se-66 | — | 42 ms | Electron capture (100%) | -41,660 keV | 8,300 keV | 1.09 × 10-14 eV |
| Se-67 | — | 133 ms | Electron capture / beta-plus decay (100%), ECP (0.5%) | -46,580.29 keV | 8,369.53 keV | 3.43 × 10-15 eV |
| Se-68 | — | 35.5 s | Electron capture / beta-plus decay (100%) | -54,189.45 keV | 8,477.05 keV | 1.29 × 10-17 eV |
| Se-69 | — | 27.4 s | Electron capture / beta-plus decay (100%), ECP (0.052%) | -56,434.71 keV | 8,503.71 keV | 1.67 × 10-17 eV |
| Se-70 | — | 41.1 m | Electron capture / beta-plus decay (100%) | -61,929.9 keV | 8,576.03 keV | 1.85 × 10-19 eV |
| Se-71 | — | 4.74 m | Electron capture / beta-plus decay (100%) | -63,146.52 keV | 8,586.06 keV | 1.60 × 10-18 eV |
| Se-72 | — | 8.40 d | Electron capture (100%) | -67,868.19 keV | 8,644.49 keV | 6.29 × 10-22 eV |
| Se-73 | — | 7.15 h | Electron capture / beta-plus decay (100%) | -68,227.4 keV | 8,641.56 keV | 1.77 × 10-20 eV |
| Se-75 | — | 119.78 d | Electron capture (100%) | -72,169.49 keV | 8,678.91 keV | 4.41 × 10-23 eV |
| Se-79 | — | 3.27E+5 Y | Beta-minus decay (100%) | -75,917.47 keV | 8,695.59 keV | 4.42 × 10-29 eV |
| Se-81 | — | 18.45 m | Beta-minus decay (100%) | -76,389.02 keV | 8,686 keV | 4.12 × 10-19 eV |
| Se-83 | — | 22.3 m | Beta-minus decay (100%) | -75,340.54 keV | 8,658.56 keV | 3.41 × 10-19 eV |
| Se-84 | — | 3.26 m | Beta-minus decay (100%) | -75,947.73 keV | 8,658.79 keV | 2.33 × 10-18 eV |
| Se-85 | — | 32.9 s | Beta-minus decay (100%) | -72,413.65 keV | 8,610.3 keV | 1.39 × 10-17 eV |
| Se-86 | — | 14.3 s | Beta-minus decay (100%) | -70,503.18 keV | 8,581.82 keV | 3.19 × 10-17 eV |
| Se-87 | — | 5.50 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.36%) | -66,426.13 keV | 8,529.09 keV | 8.30 × 10-17 eV |
| Se-88 | — | 1.53 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.99%) | -63,884.2 keV | 8,495 keV | 2.98 × 10-16 eV |
| Se-89 | — | 0.43 s | Beta-minus decay (100%), Beta-minus, neutron emission (7.8%) | -58,992.4 keV | 8,435.28 keV | 1.06 × 10-15 eV |
| Se-90 | — | 195 ms | Beta-minus decay (100%), Beta-minus, neutron emission | -55,800.22 keV | 8,395.77 keV | 2.34 × 10-15 eV |
| Se-91 | — | 0.27 s | Beta-minus decay (100%), Beta-minus, neutron emission (21%) | -50,580.13 keV | 8,334.84 keV | 1.69 × 10-15 eV |
| Se-92 | — | — | Beta-minus decay (100%) | -46,724 keV | 8,290 keV | — |
| Se-93 | — | — | Beta-minus decay (100%) | -40,860 keV | 8,225 keV | — |
| Se-94 | — | 150 ns | Beta-minus decay (100%) | -36,803 keV | 8,180 keV | 3.04 × 10-9 eV |
| Se-95 | — | 392 ns | Beta-minus decay, Beta-minus, neutron emission, B-2N | -30,460 keV | 8,112 keV | 1.16 × 10-9 eV |