Bromine
Bromine is a reddish-brown halogen and one of only two elements that exist as a liquid at room temperature, the other being mercury. It's a reactive, sharply pungent substance whose name comes from the Greek word for stench, and it sits chemically between chlorine and iodine.
- Group · Period
- 17 · 4
- At room temp
- liquid
- Melts at
- 265.95 K
- Density
- 3.11 g/cm³
- Discovered
- 1826
Uses
Bromine compounds are widely used as flame retardants, added to plastics, textiles and electronics casings to slow the spread of fire. In the oil and gas industry, dense bromide-based brines are used as drilling and completion fluids to control pressure in wells. Bromine is also a common alternative to chlorine for disinfecting swimming pools and hot tubs, valued for staying effective across a broader range of water conditions and temperatures than chlorine does.
For much of the 20th century, silver bromide was the light-sensitive compound at the heart of photographic film, and bromine compounds still find use in pharmaceuticals and specialty chemical synthesis today, though many older bromine-based products, such as certain flame retardants and leaded-gasoline additives, have been phased out over health and environmental concerns.
History
Bromine was discovered in 1826 by French chemist Antoine Balard, who isolated it from the residue of salt marsh brine near Montpellier and recognized it as a new element distinct from both chlorine and iodine. German chemist Carl Löwig independently identified the same substance around the same time while still a student, though Balard published first and is generally credited as the discoverer. The element was named bromine from the Greek word bromos, meaning stench, a fitting description of the sharp, choking odor that made it unmistakable in the laboratory.
Fun facts
- Bromine is one of only two elements that are liquid at ordinary room temperature — the other is the metal mercury.
- Its name comes from the Greek word 'bromos,' meaning stench, because of its harsh, irritating odor.
- Silver bromide's sensitivity to light made it a key ingredient in photographic film for well over a century.
Frequently asked questions
Why is bromine a liquid when most other halogens are gases?
Bromine's atoms are larger and heavier than those of fluorine and chlorine, which gives its molecules stronger intermolecular attractions. That's enough to keep it liquid at room temperature, while the lighter halogens above it remain gases and the heavier one below it, iodine, is a solid.
Is bromine dangerous to handle?
Yes — liquid bromine is corrosive to skin and its vapor is toxic and irritating to the eyes and lungs, so it's handled with protective equipment and good ventilation in labs and industry. Diluted bromine compounds used in products like pool sanitizers are far less hazardous than the pure element.
How is bromine related to chlorine?
They're both halogens in the same chemical family, so they behave similarly as oxidizers and disinfectants — bromine is often used as a chlorine alternative for sanitizing hot tubs and spas because it stays effective across a wider range of pH and temperature.
Compounds
6 notable compounds containing Br
- HBracid
Hydrobromic acid
A strong acid formed by dissolving hydrogen bromide gas in water, comparable in strength to hydrochloric acid but a stronger reducing agent.
Used for: Manufacturing bromide salts and catalyst in organic synthesis
- CH3Brorganic
Methyl bromide (bromomethane)
A colorless, odorless gas once widely used as an agricultural fumigant, now heavily restricted because it depletes stratospheric ozone.
Used for: Soil and commodity fumigant, largely phased out under the Montreal Protocol
- KBrsalt
Potassium bromide
A colorless crystalline salt transparent to infrared light, which makes it a standard window and pellet material for infrared spectroscopy.
Used for: Sample windows/pellets in IR spectroscopy; historically an anticonvulsant
- RaBr2salt
Radium bromide
A white, radioluminescent salt that the Curies used in painstaking fractional crystallizations alongside barium bromide to concentrate radium and determine its atomic weight.
Used for: Used historically to isolate and characterize radium from pitchblende ore
- AgBrsalt
Silver bromide
A pale yellow, light-sensitive salt whose crystals darken on exposure to light as silver ions are reduced to metallic silver.
Used for: Light-sensitive component of traditional photographic film
- NaBrsalt
Sodium bromide
A white crystalline salt closely related to table salt, once widely used as a sedative before safer drugs replaced it.
Used for: Source of bromide ion for photography and as a pool/spa sanitizer
Isotopes
33 known isotopes
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| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Br-79 stable | 50.65% | Stable | — | -76,068.07 keV | 8,687.6 keV | — |
| Br-81 stable | 49.35% | Stable | — | -77,977.05 keV | 8,695.95 keV | — |
Show all 33 isotopes
| Br-67 | — | — | Proton emission | -32,530 keV | 8,148 keV | — |
| Br-68 | — | 35 ns | Unknown | -38,791 keV | 8,239 keV | 1.30 × 10-8 eV |
| Br-69 | — | 24 ns | Proton emission (100%) | -46,259.48 keV | 8,344.9 keV | 1.90 × 10-8 eV |
| Br-70 | — | 79.1 ms | Electron capture / beta-plus decay (100%) | -51,425.63 keV | 8,414.8 keV | 5.77 × 10-15 eV |
| Br-71 | — | 21.4 s | Electron capture / beta-plus decay (100%) | -56,502.43 keV | 8,481.46 keV | 2.13 × 10-17 eV |
| Br-72 | — | 78.6 s | Electron capture / beta-plus decay (100%) | -59,061.75 keV | 8,511.31 keV | 5.80 × 10-18 eV |
| Br-73 | — | 3.4 m | Electron capture / beta-plus decay (100%) | -63,645.79 keV | 8,568.08 keV | 2.24 × 10-18 eV |
| Br-74 | — | 25.4 m | Electron capture / beta-plus decay (100%) | -65,288.16 keV | 8,583.56 keV | 2.99 × 10-19 eV |
| Br-75 | — | 96.7 m | Electron capture / beta-plus decay (100%) | -69,107.02 keV | 8,627.65 keV | 7.86 × 10-20 eV |
| Br-76 | — | 16.2 h | Electron capture / beta-plus decay (100%) | -70,289.08 keV | 8,635.88 keV | 7.82 × 10-21 eV |
| Br-77 | — | 57.04 h | Electron capture / beta-plus decay (100%) | -73,234.82 keV | 8,666.81 keV | 2.22 × 10-21 eV |
| Br-78 | — | 6.45 m | Electron capture / beta-plus decay (99.99%), Beta-minus decay (0.01%) | -73,452.17 keV | 8,661.96 keV | 1.18 × 10-18 eV |
| Br-80 | — | 17.68 m | Beta-minus decay (91.7%), Electron capture / beta-plus decay (8.3%) | -75,889.03 keV | 8,677.65 keV | 4.30 × 10-19 eV |
| Br-82 | — | 35.282 h | Beta-minus decay (100%) | -77,498.68 keV | 8,682.5 keV | 3.59 × 10-21 eV |
| Br-83 | — | 2.374 h | Beta-minus decay (100%) | -79,013.72 keV | 8,693.39 keV | 5.34 × 10-20 eV |
| Br-84 | — | 31.76 m | Beta-minus decay (100%) | -77,783.09 keV | 8,671.33 keV | 2.39 × 10-19 eV |
| Br-85 | — | 2.90 m | Beta-minus decay (100%) | -78,575.48 keV | 8,673.59 keV | 2.62 × 10-18 eV |
| Br-86 | — | 55.1 s | Beta-minus decay (100%) | -75,632.26 keV | 8,632.37 keV | 8.28 × 10-18 eV |
| Br-87 | — | 55.68 s | Beta-minus decay (100%), Beta-minus, neutron emission (2.6%) | -73,891.69 keV | 8,605.91 keV | 8.19 × 10-18 eV |
| Br-88 | — | 16.34 s | Beta-minus decay (100%), Beta-minus, neutron emission (6.58%) | -70,715.97 keV | 8,563.75 keV | 2.79 × 10-17 eV |
| Br-89 | — | 4.357 s | Beta-minus decay (100%), Beta-minus, neutron emission (13.7%) | -68,274.27 keV | 8,530.78 keV | 1.05 × 10-16 eV |
| Br-90 | — | 1.91 s | Beta-minus decay (100%), Beta-minus, neutron emission (25.3%) | -64,000.31 keV | 8,478.19 keV | 2.39 × 10-16 eV |
| Br-91 | — | 0.543 s | Beta-minus decay (100%), Beta-minus, neutron emission (19.5%) | -61,107.3 keV | 8,441.92 keV | 8.40 × 10-16 eV |
| Br-92 | — | 0.314 s | Beta-minus decay (100%), Beta-minus, neutron emission (33.1%) | -56,232.81 keV | 8,384.91 keV | 1.45 × 10-15 eV |
| Br-93 | — | 102 ms | Beta-minus decay (100%), Beta-minus, neutron emission (68%) | -52,890.24 keV | 8,345.6 keV | 4.47 × 10-15 eV |
| Br-94 | — | 70 ms | Beta-minus decay (100%), Beta-minus, neutron emission (68%) | -47,650 keV | 8,287 keV | 6.52 × 10-15 eV |
| Br-95 | — | 150 ns | Beta-minus decay (100%), Beta-minus, neutron emission (34%) | -43,850 keV | 8,245 keV | 3.04 × 10-9 eV |
| Br-96 | — | 150 ns | Beta-minus decay (100%), Beta-minus, neutron emission (27.6%) | -38,210 keV | 8,184 keV | 3.04 × 10-9 eV |
| Br-97 | — | — | Beta-minus decay (100%), B-2N, Beta-minus, neutron emission | -34,000 keV | 8,140 keV | — |
| Br-98 | — | — | Beta-minus decay (100%), B-2N, B-3N | -28,050 keV | 8,078 keV | — |
| Br-101 | — | — | Beta-minus decay (100%), B-2N, B-3N | — | — | — |