Praseodymium
Praseodymium is a soft, silvery rare-earth metal discovered by splitting apart what chemists had long believed was a single element into two distinct ones. Its name reflects the green tint of its salts, and today it's best known for coloring glass and ceramics and for strengthening aerospace alloys.
- Group · Period
- — · 6
- At room temp
- solid
- Melts at
- 1204 K
- Density
- 6.77 g/cm³
- Discovered
- 1885
Uses
Praseodymium compounds are used to add a rich yellow-green color to glass and ceramic glazes, valued both for decorative purposes and for filtering specific wavelengths of light. Combined with neodymium in a formulation known as didymium glass, praseodymium is a core ingredient in the protective eyewear used by glassblowers and welders, since the glass filters out the intense sodium-flame glare and infrared heat produced by molten glass and welding arcs.
Praseodymium is also alloyed with magnesium to create lightweight, high-strength materials used in aircraft engine components, and small amounts are sometimes blended into neodymium-based permanent magnets to adjust their performance.
History
Praseodymium’s discovery came out of a decades-long puzzle. In the 1840s, chemists had identified a substance called didymium that seemed to be a new element found alongside lanthanum and cerium, but its properties never quite added up consistently across different samples. In 1885, Austrian chemist Carl Auer von Welsbach finally showed why: using repeated chemical separation, he demonstrated that didymium was actually a blend of two distinct elements. He named the new pair praseodymium, from Greek words meaning “green twin,” for the color of its salts, and neodymium, meaning “new twin,” resolving a mystery that had puzzled chemists for nearly forty years.
Fun facts
- Praseodymium was discovered by splitting a substance called 'didymium,' long thought to be one element, into two new elements: praseodymium and neodymium.
- Its name comes from Greek words meaning 'green twin,' describing the color of its salts and its close relationship to neodymium.
- Glass containing praseodymium and neodymium, called didymium glass, is used to make the protective goggles worn by glassblowers and welders.
Frequently asked questions
What is 'didymium' and how is it connected to praseodymium?
Didymium was the name chemists gave in the 1840s to a substance found alongside lanthanum and cerium that they believed was a single new element. It took decades of increasingly careful chemical separation before Carl Auer von Welsbach showed in 1885 that didymium was actually a mixture of two distinct elements, which he named praseodymium and neodymium.
Is praseodymium used in magnets?
It can be, though usually as a minor addition alongside neodymium rather than the main ingredient. Praseodymium is sometimes alloyed into neodymium-iron-boron magnets to fine-tune their strength and resistance to heat, since the two elements are chemically similar and were discovered together in the same experiment.
Why is praseodymium glass used for welding and glassblowing goggles?
Glass containing praseodymium, usually combined with neodymium, has the useful property of filtering out the intense yellow sodium light and infrared radiation given off by molten glass and welding arcs, while still letting the wearer see clearly. That selective filtering protects the eyes from glare and heat without blocking vision the way fully dark goggles would.
Compounds
3 notable compounds containing Pr
- PrF3halide
Praseodymium fluoride
A green, insoluble crystalline solid used as a doping additive to modify the color and properties of specialty optical glass and ceramics.
Used for: Additive in specialty optical glass and ceramic formulations
- Pr6O11oxide
Praseodymium oxide
A dark brown-black mixed-valence oxide, the stable form praseodymium metal adopts on exposure to air, prized for producing a distinctive yellow color in glass and ceramics.
Used for: Yellow colorant in glass, enamel, and ceramic glazes
- PrCl3halide
Praseodymium(III) chloride
A light green, hygroscopic salt that provides the standard water-soluble route into praseodymium chemistry.
Used for: Laboratory precursor for praseodymium compounds
Isotopes
39 known isotopes
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| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Pr-141 stable | 100% | Stable | — | -86,014.53 keV | 8,353.99 keV | — |
Show all 39 isotopes
| Pr-121 | — | 10 ms | Proton emission (100%) | -41,551 keV | 8,033 keV | 4.56 × 10-14 eV |
| Pr-124 | — | 1.2 s | Electron capture / beta-plus decay (100%), ECP (0%) | -53,151 keV | 8,128 keV | 3.80 × 10-16 eV |
| Pr-125 | — | 3.3 s | Electron capture / beta-plus decay (100%), Beta-plus, proton emission | -58,070 keV | 8,167 keV | 1.38 × 10-16 eV |
| Pr-126 | — | 3.14 s | Electron capture / beta-plus decay (100%), ECP | -60,324 keV | 8,184 keV | 1.45 × 10-16 eV |
| Pr-127 | — | 4.2 s | Electron capture / beta-plus decay (100%) | -64,543 keV | 8,216 keV | 1.09 × 10-16 eV |
| Pr-128 | — | 2.84 s | Electron capture / beta-plus decay (100%) | -66,330.76 keV | 8,228.91 keV | 1.61 × 10-16 eV |
| Pr-129 | — | 30 s | Electron capture / beta-plus decay (100%) | -69,773.57 keV | 8,254.38 keV | 1.52 × 10-17 eV |
| Pr-130 | — | 40.0 s | Electron capture / beta-plus decay (100%) | -71,175.46 keV | 8,263.76 keV | 1.14 × 10-17 eV |
| Pr-131 | — | 1.51 m | Electron capture / beta-plus decay (100%) | -74,300.66 keV | 8,286.14 keV | 5.04 × 10-18 eV |
| Pr-132 | — | 1.6 m | Electron capture / beta-plus decay (100%) | -75,227.46 keV | 8,291.54 keV | 4.75 × 10-18 eV |
| Pr-133 | — | 6.5 m | Electron capture / beta-plus decay (100%) | -77,937.59 keV | 8,310.26 keV | 1.17 × 10-18 eV |
| Pr-134 | — | 17 m | Electron capture / beta-plus decay (100%) | -78,528 keV | 8,312.88 keV | 4.47 × 10-19 eV |
| Pr-135 | — | 24 m | Electron capture / beta-plus decay (100%) | -80,935.87 keV | 8,328.93 keV | 3.17 × 10-19 eV |
| Pr-136 | — | 13.1 m | Electron capture / beta-plus decay (100%) | -81,340.42 keV | 8,330.01 keV | 5.80 × 10-19 eV |
| Pr-137 | — | 1.28 h | Electron capture / beta-plus decay (100%) | -83,201.81 keV | 8,341.71 keV | 9.90 × 10-20 eV |
| Pr-138 | — | 1.45 m | Electron capture / beta-plus decay (100%) | -83,128.87 keV | 8,339.22 keV | 5.24 × 10-18 eV |
| Pr-139 | — | 4.41 h | Electron capture / beta-plus decay (100%) | -84,828.65 keV | 8,349.52 keV | 2.87 × 10-20 eV |
| Pr-140 | — | 3.39 m | Electron capture / beta-plus decay (100%) | -84,686.23 keV | 8,346.52 keV | 2.24 × 10-18 eV |
| Pr-142 | — | 19.12 h | Beta-minus decay (99.9836%), Electron capture (0.0164%) | -83,786.37 keV | 8,336.3 keV | 6.63 × 10-21 eV |
| Pr-143 | — | 13.57 d | Beta-minus decay (100%) | -83,068.2 keV | 8,329.43 keV | 3.89 × 10-22 eV |
| Pr-144 | — | 17.28 m | Beta-minus decay (100%) | -80,750.59 keV | 8,311.54 keV | 4.40 × 10-19 eV |
| Pr-145 | — | 5.984 h | Beta-minus decay (100%) | -79,625.99 keV | 8,302.13 keV | 2.12 × 10-20 eV |
| Pr-146 | — | 24.09 m | Beta-minus decay (100%) | -76,673.49 keV | 8,280.33 keV | 3.16 × 10-19 eV |
| Pr-147 | — | 13.44 m | Beta-minus decay (100%) | -75,444.09 keV | 8,270.54 keV | 5.66 × 10-19 eV |
| Pr-148 | — | 2.29 m | Beta-minus decay (100%) | -72,535.45 keV | 8,249.54 keV | 3.32 × 10-18 eV |
| Pr-149 | — | 2.26 m | Beta-minus decay (100%) | -71,039.37 keV | 8,238.3 keV | 3.36 × 10-18 eV |
| Pr-150 | — | 6.19 s | Beta-minus decay (100%) | -68,300.51 keV | 8,218.93 keV | 7.37 × 10-17 eV |
| Pr-151 | — | 18.90 s | Beta-minus decay (100%) | -66,779.68 keV | 8,207.88 keV | 2.41 × 10-17 eV |
| Pr-152 | — | 3.57 s | Beta-minus decay (100%) | -63,758.07 keV | 8,187.1 keV | 1.28 × 10-16 eV |
| Pr-153 | — | 4.29 s | Beta-minus decay (100%), Beta-minus, neutron emission | -61,568.49 keV | 8,172.04 keV | 1.06 × 10-16 eV |
| Pr-154 | — | 2.3 s | Beta-minus decay (100%) | -57,859.6 keV | 8,147.3 keV | 1.98 × 10-16 eV |
| Pr-155 | — | 1.47 s | Beta-minus decay (100%), Beta-minus, neutron emission | -55,415.34 keV | 8,131.04 keV | 3.10 × 10-16 eV |
| Pr-156 | — | 0.444 s | Beta-minus decay (100%), Beta-minus, neutron emission | -51,449.31 keV | 8,105.23 keV | 1.03 × 10-15 eV |
| Pr-157 | — | 0.295 s | Beta-minus decay (100%), Beta-minus, neutron emission | -48,434.81 keV | 8,085.82 keV | 1.55 × 10-15 eV |
| Pr-158 | — | 0.181 s | Beta-minus decay (100%), Beta-minus, neutron emission | -44,150 keV | 8,059 keV | 2.52 × 10-15 eV |
| Pr-159 | — | 0.13 s | Beta-minus decay (100%), Beta-minus, neutron emission | -40,770 keV | 8,037 keV | 3.51 × 10-15 eV |
| Pr-160 | — | 0.17 s | Beta-minus decay (100%), Beta-minus, neutron emission | -36,200 keV | 8,009 keV | 2.68 × 10-15 eV |
| Pr-161 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission | -32,490 keV | 7,986 keV | — |