Lanthanum
Lanthanum is a soft, silvery metal and the element that lends its name to the entire lanthanide series of 15 similar elements. It was discovered hiding within what chemists thought was pure cerium, and today it's valued for improving the optical quality of glass and for its role in rechargeable battery technology.
- Group · Period
- — · 6
- At room temp
- solid
- Melts at
- 1191 K
- Density
- 6.15 g/cm³
- Discovered
- 1839
Uses
Lanthanum’s most distinctive application is in optical glass: adding lanthanum oxide raises the glass’s refractive index while limiting chromatic aberration, so it’s used in higher-quality camera lenses, telescopes, and other precision optics where sharper, more accurate images matter. Lanthanum-based alloys are also a core component of nickel-metal hydride batteries, which store and release energy through a hydrogen-absorbing electrode and became especially well known for powering early hybrid vehicles.
In the petroleum industry, lanthanum-containing catalysts play a role in fluid catalytic cracking, a process refineries use to break heavy crude oil fractions down into more valuable, lighter fuels.
History
Lanthanum was discovered in 1839 by Swedish chemist Carl Gustaf Mosander, who was investigating what other chemists believed to be pure cerium nitrate and found that it actually contained a second, previously unrecognized element mixed in. He named it lanthanum, from the Greek lanthanein, meaning “to lie hidden,” a nod to how long it had gone unnoticed within cerium samples. That discovery turned out to be the first crack in a much bigger puzzle, as Mosander and later chemists went on to find several more closely related elements hiding in the same minerals — the group that lanthanum eventually gave its name to.
Fun facts
- Lanthanum gives its name to the whole 'lanthanide' series of 15 chemically similar elements that sit together on the periodic table.
- Small amounts of lanthanum oxide are added to optical glass in camera and telescope lenses to sharpen images and reduce distortion.
- Lanthanum alloys are a key ingredient in nickel-metal hydride (NiMH) batteries, once widely used in hybrid vehicles and rechargeable household batteries.
Frequently asked questions
Why is lanthanum considered the 'first' rare-earth element even though it was hidden in another one?
Lanthanum was discovered as an unexpected impurity within cerium compounds, which is exactly why it got its name — from a Greek word meaning "to lie hidden." Once chemists isolated it, they realized it shared enough chemical behavior with the elements that came after it in the periodic table that the whole group of fifteen similar elements came to be called lanthanides, after it.
What does lanthanum have to do with batteries?
Lanthanum, usually combined with other rare-earth elements in an alloy, forms the metal hydride electrode used in nickel-metal hydride (NiMH) batteries. That electrode can absorb and release hydrogen atoms as the battery charges and discharges, which is the basic mechanism that made NiMH batteries a popular, more environmentally friendly alternative to older nickel-cadmium cells.
What is lanthanum glass used for?
Adding lanthanum oxide to optical glass raises its refractive index without adding as much unwanted color distortion as some other additives do, which lets lens designers create sharper, higher quality images with fewer glass elements. That's why lanthanum glass shows up in higher-end camera lenses, microscopes and other precision optical instruments.
Compounds
4 notable compounds containing La
- La2(CO3)3pharmaceutical
Lanthanum carbonate
An insoluble lanthanum salt taken orally to bind excess dietary phosphate in the gut, passing through the digestive tract largely unabsorbed.
Used for: Phosphate-binding medication for kidney dialysis patients
- LaF3halide
Lanthanum fluoride
An insoluble crystalline solid whose ion-conducting properties make it the active membrane material in fluoride-selective electrodes.
Used for: Membrane material in fluoride ion-selective electrodes
- La2O3oxide
Lanthanum oxide
A white, air-stable oxide and lanthanum's standard commercial form, used to fine-tune the refractive index of specialty optical glass.
Used for: Component of high-refractive-index camera and telescope lens glass
- LaCl3halide
Lanthanum(III) chloride
A white, hygroscopic salt that serves as the standard water-soluble entry point into lanthanum chemistry.
Used for: Laboratory precursor for lanthanum compounds and catalysts
Isotopes
39 known isotopes
Swipe to see all columns →
| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| La-138 | 0.08881% | 1.03E+11 Y | Electron capture / beta-plus decay (65.5%), Beta-minus decay (34.5%) | -86,513.41 keV | 8,375.08 keV | 1.40 × 10-34 eV |
| La-139 stable | 99.91119% | Stable | — | -87,222.38 keV | 8,378 keV | — |
Show all 39 isotopes
| La-117 | — | 23.5 ms | Proton emission (93.9%), Electron capture / beta-plus decay (6.1%) | -46,271 keV | 8,086 keV | 1.94 × 10-14 eV |
| La-120 | — | 2.8 s | Electron capture / beta-plus decay (100%), ECP (0%) | -57,570 keV | 8,179 keV | 1.63 × 10-16 eV |
| La-121 | — | 5.3 s | Electron capture / beta-plus decay (100%) | -62,190 keV | 8,217 keV | 8.61 × 10-17 eV |
| La-122 | — | 8.6 s | Electron capture / beta-plus decay (100%), ECP | -64,543 keV | 8,235 keV | 5.31 × 10-17 eV |
| La-123 | — | 16.3 s | Electron capture / beta-plus decay (100%) | -68,651 keV | 8,267 keV | 2.80 × 10-17 eV |
| La-124 | — | 21 s | Electron capture / beta-plus decay (100%) | -70,258.62 keV | 8,278.29 keV | 2.17 × 10-17 eV |
| La-125 | — | 64.8 s | Electron capture / beta-plus decay (100%) | -73,759.49 keV | 8,304.64 keV | 7.04 × 10-18 eV |
| La-126 | — | 54 s | Electron capture / beta-plus decay (0%) | -74,973.48 keV | 8,312.43 keV | 8.45 × 10-18 eV |
| La-127 | — | 5.1 m | Electron capture / beta-plus decay (100%) | -77,896.12 keV | 8,333.54 keV | 1.49 × 10-18 eV |
| La-128 | — | 5.18 m | Electron capture (100%) | -78,625.44 keV | 8,337.19 keV | 1.47 × 10-18 eV |
| La-129 | — | 11.6 m | Electron capture / beta-plus decay (100%) | -81,323.54 keV | 8,356.04 keV | 6.56 × 10-19 eV |
| La-130 | — | 8.7 m | Electron capture / beta-plus decay (100%) | -81,627.37 keV | 8,356.19 keV | 8.74 × 10-19 eV |
| La-131 | — | 59 m | Electron capture / beta-plus decay (100%) | -83,769.27 keV | 8,370.37 keV | 1.29 × 10-19 eV |
| La-132 | — | 4.8 h | Electron capture / beta-plus decay (100%) | -83,723.58 keV | 8,367.76 keV | 2.64 × 10-20 eV |
| La-133 | — | 3.912 h | Electron capture / beta-plus decay (100%) | -85,494.39 keV | 8,378.84 keV | 3.24 × 10-20 eV |
| La-134 | — | 6.45 m | Electron capture / beta-plus decay (100%) | -85,218.66 keV | 8,374.49 keV | 1.18 × 10-18 eV |
| La-135 | — | 19.5 h | Electron capture / beta-plus decay (100%) | -86,643.46 keV | 8,382.8 keV | 6.50 × 10-21 eV |
| La-136 | — | 9.87 m | Electron capture / beta-plus decay (100%) | -86,037.49 keV | 8,376.05 keV | 7.70 × 10-19 eV |
| La-137 | — | 6E+4 Y | Electron capture (100%) | -87,140.87 keV | 8,381.88 keV | 2.41 × 10-28 eV |
| La-140 | — | 1.67858 d | Beta-minus decay (100%) | -84,312.06 keV | 8,355.02 keV | 3.15 × 10-21 eV |
| La-141 | — | 3.92 h | Beta-minus decay (100%) | -82,929.84 keV | 8,343.21 keV | 3.23 × 10-20 eV |
| La-142 | — | 91.1 m | Beta-minus decay (100%) | -80,023.95 keV | 8,320.83 keV | 8.35 × 10-20 eV |
| La-143 | — | 14.2 m | Beta-minus decay (100%) | -78,171.47 keV | 8,306.13 keV | 5.35 × 10-19 eV |
| La-144 | — | 40.8 s | Beta-minus decay (100%) | -74,849.66 keV | 8,281.43 keV | 1.12 × 10-17 eV |
| La-145 | — | 24.8 s | Beta-minus decay (100%) | -72,835.33 keV | 8,266.09 keV | 1.84 × 10-17 eV |
| La-146 | — | 6.1 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.007%) | -69,221.17 keV | 8,240 keV | 7.48 × 10-17 eV |
| La-147 | — | 4.06 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.041%) | -66,678.4 keV | 8,221.55 keV | 1.12 × 10-16 eV |
| La-148 | — | 1.26 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.15%) | -62,708.74 keV | 8,193.72 keV | 3.62 × 10-16 eV |
| La-149 | — | 1.091 s | Beta-minus decay (100%), Beta-minus, neutron emission (1.41%) | -60,219.92 keV | 8,176.19 keV | 4.18 × 10-16 eV |
| La-150 | — | 0.59 s | Beta-minus decay (100%), Beta-minus, neutron emission (2.7%) | -56,311.15 keV | 8,149.43 keV | 7.73 × 10-16 eV |
| La-151 | — | 0.457 s | Beta-minus decay (100%), Beta-minus, neutron emission | -53,310.34 keV | 8,129.04 keV | 9.98 × 10-16 eV |
| La-152 | — | 0.298 s | Beta-minus decay (100%), Beta-minus, neutron emission | -49,290 keV | 8,102 keV | 1.53 × 10-15 eV |
| La-153 | — | 0.245 s | Beta-minus decay (100%), Beta-minus, neutron emission | -46,060 keV | 8,081 keV | 1.86 × 10-15 eV |
| La-154 | — | 0.161 s | Beta-minus decay (100%), Beta-minus, neutron emission | -41,530 keV | 8,051 keV | 2.83 × 10-15 eV |
| La-155 | — | 101 ms | Beta-minus decay (100%), Beta-minus, neutron emission | -37,930 keV | 8,028 keV | 4.52 × 10-15 eV |
| La-156 | — | 84 ms | Beta-minus decay (100%), Beta-minus, neutron emission | -33,050 keV | 7,997 keV | 5.43 × 10-15 eV |
| La-157 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | -29,070 keV | 7,972 keV | — |