50Sn118.71
Post-transition metal

Tin

Tin is a soft, silvery-white metal that played an outsized role in early human history — alloying it with copper to make bronze gave the Bronze Age its name. It resists corrosion well, is easy to melt and shape, and bending a bar of it produces a distinctive crackling sound known as the "tin cry."

Group · Period
14 · 5
At room temp
solid
Melts at
505.08 K
Density
7.287 g/cm³
Discovered
Ancient

Uses

Tin’s oldest and most historically important use is as the key ingredient in bronze, an alloy with copper that ancient civilizations discovered was far harder and more workable than either metal alone. Today, tin’s best-known job is protecting steel: a thin electroplated layer of tin on steel sheet — what most people call a “tin can” — keeps food and beverage containers from rusting, since tin resists corrosion much better than bare steel while still being safe to have in contact with food.

Tin is also a core ingredient in solder, the low-melting alloy used to join electrical components and pipework; lead-free solders based on tin, copper and silver have become standard in electronics as regulations have phased out older tin-lead formulas. It’s additionally used in pewter, a tin-based alloy long favored for tableware and decorative objects.

History

Tin has been used since antiquity, well before it could be credited to any single discoverer. Its major historical breakthrough came when ancient metalworkers, independently in several regions, learned to alloy tin with copper to make bronze — a harder, more durable material that gave its name to the Bronze Age and transformed toolmaking and warfare. Tin ore was valuable enough that it was traded across long distances in the ancient world, connecting regions that otherwise had little contact. Its chemical symbol, Sn, comes from its Latin name, stannum, reflecting how long the metal has been part of recorded human history.

Fun facts

  • Alloying tin with copper produces bronze, one of the first engineered metal alloys in human history and the namesake of the Bronze Age.
  • Bending a bar of pure tin produces an audible crackling sound called the tin cry, caused by crystals inside the metal shifting against each other.
  • So-called tin cans are actually made mostly of steel, with only a thin coating of tin applied to stop the steel underneath from rusting.

Frequently asked questions

Are tin cans actually made of tin?

Not mostly, no. A "tin can" is really a steel can with a very thin layer of tin plated onto it. The steel provides the strength and keeps costs low, while the tin coating stops the steel from corroding when it contacts food, since tin resists rusting far better than bare steel does.

What causes the 'tin cry' sound?

Pure tin is made of large crystal grains, and when a bar of it is bent, those crystals deform by shifting into new orientations called twins. Each tiny shift releases a small crack of sound, and many of these happening in quick succession produce the audible crackling "cry" that tin is known for.

Why was tin so important before modern chemistry existed?

On its own, tin is soft and not especially useful for tools. But mixed with copper in roughly the right proportions, it produces bronze — a much harder, more durable metal that could be cast into sharp, long-lasting tools and weapons. That discovery, made independently by several ancient cultures, was significant enough to define an entire era of human technology.

Compounds

4 notable compounds containing Sn

  • SnCl2halide

    Tin(II) chloride

    A white crystalline reducing agent, also called stannous chloride, that readily oxidizes to tin(IV) when exposed to air or moisture.

    Used for: Reducing agent in chemical analysis and tin-based mirror silvering

  • SnF2halide

    Tin(II) fluoride

    A water-soluble tin salt, commonly called stannous fluoride, that delivers fluoride ions to strengthen tooth enamel against decay.

    Used for: Active ingredient in fluoride toothpaste

  • SnCl4halide

    Tin(IV) chloride

    A colorless, fuming liquid, also known as stannic chloride, that reacts vigorously with water and was once used as a smoke-screen agent.

    Used for: Catalyst in organic synthesis and precursor for tin oxide coatings

  • SnO2oxide

    Tin(IV) oxide

    A hard, chemically stable oxide that occurs naturally as the mineral cassiterite, the principal ore from which tin metal is extracted.

    Used for: Ore of tin metal and abrasive/polishing compound

Isotopes

42 known isotopes

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IsotopeNatural abundanceHalf-lifeDecay modeMass excessBinding energy / nucleonDecay width
Sn-112 stable 0.97% Stable -88,655.05 keV 8,513.62 keV
Sn-114 stable 0.66% Stable -90,559.74 keV 8,522.57 keV
Sn-115 stable 0.34% Stable -90,033.85 keV 8,514.07 keV
Sn-116 stable 14.54% Stable -91,525.98 keV 8,523.12 keV
Sn-117 stable 7.68% Stable -90,397.74 keV 8,509.61 keV
Sn-118 stable 24.22% Stable -91,652.84 keV 8,516.53 keV
Sn-119 stable 8.59% Stable -90,064.99 keV 8,499.45 keV
Sn-120 stable 32.58% Stable -91,097.74 keV 8,504.49 keV
Sn-122 stable 4.63% Stable -89,939.95 keV 8,487.9 keV
Sn-124 stable 5.79% Stable -88,231.48 keV 8,467.4 keV
Show all 42 isotopes
Sn-99 760 ns Electron capture / beta-plus decay, ECP -47,976 keV 8,161 keV 6.00 × 10-10 eV
Sn-100 1.18 s Electron capture / beta-plus decay (100%), ECP (17%) -57,148.15 keV 8,251.63 keV 3.87 × 10-16 eV
Sn-101 1.7 s Electron capture / beta-plus decay (100%), ECP (26%) -60,305.62 keV 8,281.1 keV 2.68 × 10-16 eV
Sn-102 3.8 s Electron capture / beta-plus decay (100%) -64,934.9 keV 8,324.43 keV 1.20 × 10-16 eV
Sn-103 7.0 s Electron capture / beta-plus decay (100%), ECP (1.2%) -67,092 keV 8,343 keV 6.52 × 10-17 eV
Sn-104 20.8 s Electron capture / beta-plus decay (100%) -71,627.06 keV 8,383.91 keV 2.19 × 10-17 eV
Sn-105 32.7 s Electron capture / beta-plus decay (100%), Beta-plus, proton emission (0.011%) -73,338 keV 8,397.23 keV 1.40 × 10-17 eV
Sn-106 115 s Electron capture / beta-plus decay (100%) -77,353.7 keV 8,432.04 keV 3.97 × 10-18 eV
Sn-107 2.90 m Electron capture / beta-plus decay (100%) -78,512.24 keV 8,439.49 keV 2.62 × 10-18 eV
Sn-108 10.30 m Electron capture / beta-plus decay (100%) -82,069.95 keV 8,469.03 keV 7.38 × 10-19 eV
Sn-109 18.1 m Electron capture / beta-plus decay (100%) -82,630.18 keV 8,470.52 keV 4.20 × 10-19 eV
Sn-110 4.154 h Electron capture (100%) -85,841.99 keV 8,496.09 keV 3.05 × 10-20 eV
Sn-111 35.3 m Electron capture / beta-plus decay (100%) -85,938.58 keV 8,493.13 keV 2.15 × 10-19 eV
Sn-113 115.09 d Electron capture / beta-plus decay (100%) -88,328.13 keV 8,506.81 keV 4.59 × 10-23 eV
Sn-121 27.03 h Beta-minus decay (100%) -89,196.63 keV 8,485.2 keV 4.69 × 10-21 eV
Sn-123 129.2 d Beta-minus decay (100%) -87,814.68 keV 8,467.23 keV 4.09 × 10-23 eV
Sn-125 9.64 d Beta-minus decay (100%) -85,893.66 keV 8,445.53 keV 5.48 × 10-22 eV
Sn-126 2.18E+5 Y Beta-minus decay (100%) -86,015.14 keV 8,443.52 keV 6.63 × 10-29 eV
Sn-127 2.10 h Beta-minus decay (100%) -83,469.58 keV 8,420.55 keV 6.03 × 10-20 eV
Sn-128 59.07 m Beta-minus decay (100%) -83,361.43 keV 8,416.97 keV 1.29 × 10-19 eV
Sn-129 2.23 m Beta-minus decay (100%) -80,590.6 keV 8,392.82 keV 3.41 × 10-18 eV
Sn-130 3.72 m Beta-minus decay (100%) -80,132.22 keV 8,386.82 keV 2.04 × 10-18 eV
Sn-131 56.0 s Beta-minus decay (100%) -77,264.58 keV 8,362.52 keV 8.15 × 10-18 eV
Sn-132 39.7 s Beta-minus decay (100%) -76,546.55 keV 8,354.87 keV 1.15 × 10-17 eV
Sn-133 1.46 s Beta-minus decay (100%), Beta-minus, neutron emission (0.0294%) -70,873.89 keV 8,310.09 keV 3.12 × 10-16 eV
Sn-134 1.050 s Beta-minus decay (100%), Beta-minus, neutron emission (17%) -66,433.76 keV 8,275.17 keV 4.35 × 10-16 eV
Sn-135 515 ms Beta-minus decay (100%), Beta-minus, neutron emission (21%), B-2N -60,632.25 keV 8,230.69 keV 8.86 × 10-16 eV
Sn-136 345 ms Beta-minus decay (100%), Beta-minus, neutron emission (27%) -56,170 keV 8,197 keV 1.32 × 10-15 eV
Sn-137 190 ms Beta-minus decay (100%), Beta-minus, neutron emission (58%) -50,150 keV 8,152 keV 2.40 × 10-15 eV
Sn-138 140 ms Beta-minus decay (100%), Beta-minus, neutron emission (36%), B-2N -45,510 keV 8,118 keV 3.26 × 10-15 eV
Sn-139 130 ms Beta-minus decay (100%), Beta-minus, neutron emission, B-3N -39,310 keV 8,073 keV 3.51 × 10-15 eV
Sn-140 Beta-minus decay (100%), Beta-minus, neutron emission, B-2N -34,490 keV 8,038 keV