Tin
Tin is a soft, silvery-white metal that played an outsized role in early human history — alloying it with copper to make bronze gave the Bronze Age its name. It resists corrosion well, is easy to melt and shape, and bending a bar of it produces a distinctive crackling sound known as the "tin cry."
- Group · Period
- 14 · 5
- At room temp
- solid
- Melts at
- 505.08 K
- Density
- 7.287 g/cm³
- Discovered
- Ancient
Uses
Tin’s oldest and most historically important use is as the key ingredient in bronze, an alloy with copper that ancient civilizations discovered was far harder and more workable than either metal alone. Today, tin’s best-known job is protecting steel: a thin electroplated layer of tin on steel sheet — what most people call a “tin can” — keeps food and beverage containers from rusting, since tin resists corrosion much better than bare steel while still being safe to have in contact with food.
Tin is also a core ingredient in solder, the low-melting alloy used to join electrical components and pipework; lead-free solders based on tin, copper and silver have become standard in electronics as regulations have phased out older tin-lead formulas. It’s additionally used in pewter, a tin-based alloy long favored for tableware and decorative objects.
History
Tin has been used since antiquity, well before it could be credited to any single discoverer. Its major historical breakthrough came when ancient metalworkers, independently in several regions, learned to alloy tin with copper to make bronze — a harder, more durable material that gave its name to the Bronze Age and transformed toolmaking and warfare. Tin ore was valuable enough that it was traded across long distances in the ancient world, connecting regions that otherwise had little contact. Its chemical symbol, Sn, comes from its Latin name, stannum, reflecting how long the metal has been part of recorded human history.
Fun facts
- Alloying tin with copper produces bronze, one of the first engineered metal alloys in human history and the namesake of the Bronze Age.
- Bending a bar of pure tin produces an audible crackling sound called the tin cry, caused by crystals inside the metal shifting against each other.
- So-called tin cans are actually made mostly of steel, with only a thin coating of tin applied to stop the steel underneath from rusting.
Frequently asked questions
Are tin cans actually made of tin?
Not mostly, no. A "tin can" is really a steel can with a very thin layer of tin plated onto it. The steel provides the strength and keeps costs low, while the tin coating stops the steel from corroding when it contacts food, since tin resists rusting far better than bare steel does.
What causes the 'tin cry' sound?
Pure tin is made of large crystal grains, and when a bar of it is bent, those crystals deform by shifting into new orientations called twins. Each tiny shift releases a small crack of sound, and many of these happening in quick succession produce the audible crackling "cry" that tin is known for.
Why was tin so important before modern chemistry existed?
On its own, tin is soft and not especially useful for tools. But mixed with copper in roughly the right proportions, it produces bronze — a much harder, more durable metal that could be cast into sharp, long-lasting tools and weapons. That discovery, made independently by several ancient cultures, was significant enough to define an entire era of human technology.
Compounds
4 notable compounds containing Sn
- SnCl2halide
Tin(II) chloride
A white crystalline reducing agent, also called stannous chloride, that readily oxidizes to tin(IV) when exposed to air or moisture.
Used for: Reducing agent in chemical analysis and tin-based mirror silvering
- SnF2halide
Tin(II) fluoride
A water-soluble tin salt, commonly called stannous fluoride, that delivers fluoride ions to strengthen tooth enamel against decay.
Used for: Active ingredient in fluoride toothpaste
- SnCl4halide
Tin(IV) chloride
A colorless, fuming liquid, also known as stannic chloride, that reacts vigorously with water and was once used as a smoke-screen agent.
Used for: Catalyst in organic synthesis and precursor for tin oxide coatings
- SnO2oxide
Tin(IV) oxide
A hard, chemically stable oxide that occurs naturally as the mineral cassiterite, the principal ore from which tin metal is extracted.
Used for: Ore of tin metal and abrasive/polishing compound
Isotopes
42 known isotopes
Swipe to see all columns →
| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Sn-112 stable | 0.97% | Stable | — | -88,655.05 keV | 8,513.62 keV | — |
| Sn-114 stable | 0.66% | Stable | — | -90,559.74 keV | 8,522.57 keV | — |
| Sn-115 stable | 0.34% | Stable | — | -90,033.85 keV | 8,514.07 keV | — |
| Sn-116 stable | 14.54% | Stable | — | -91,525.98 keV | 8,523.12 keV | — |
| Sn-117 stable | 7.68% | Stable | — | -90,397.74 keV | 8,509.61 keV | — |
| Sn-118 stable | 24.22% | Stable | — | -91,652.84 keV | 8,516.53 keV | — |
| Sn-119 stable | 8.59% | Stable | — | -90,064.99 keV | 8,499.45 keV | — |
| Sn-120 stable | 32.58% | Stable | — | -91,097.74 keV | 8,504.49 keV | — |
| Sn-122 stable | 4.63% | Stable | — | -89,939.95 keV | 8,487.9 keV | — |
| Sn-124 stable | 5.79% | Stable | — | -88,231.48 keV | 8,467.4 keV | — |
Show all 42 isotopes
| Sn-99 | — | 760 ns | Electron capture / beta-plus decay, ECP | -47,976 keV | 8,161 keV | 6.00 × 10-10 eV |
| Sn-100 | — | 1.18 s | Electron capture / beta-plus decay (100%), ECP (17%) | -57,148.15 keV | 8,251.63 keV | 3.87 × 10-16 eV |
| Sn-101 | — | 1.7 s | Electron capture / beta-plus decay (100%), ECP (26%) | -60,305.62 keV | 8,281.1 keV | 2.68 × 10-16 eV |
| Sn-102 | — | 3.8 s | Electron capture / beta-plus decay (100%) | -64,934.9 keV | 8,324.43 keV | 1.20 × 10-16 eV |
| Sn-103 | — | 7.0 s | Electron capture / beta-plus decay (100%), ECP (1.2%) | -67,092 keV | 8,343 keV | 6.52 × 10-17 eV |
| Sn-104 | — | 20.8 s | Electron capture / beta-plus decay (100%) | -71,627.06 keV | 8,383.91 keV | 2.19 × 10-17 eV |
| Sn-105 | — | 32.7 s | Electron capture / beta-plus decay (100%), Beta-plus, proton emission (0.011%) | -73,338 keV | 8,397.23 keV | 1.40 × 10-17 eV |
| Sn-106 | — | 115 s | Electron capture / beta-plus decay (100%) | -77,353.7 keV | 8,432.04 keV | 3.97 × 10-18 eV |
| Sn-107 | — | 2.90 m | Electron capture / beta-plus decay (100%) | -78,512.24 keV | 8,439.49 keV | 2.62 × 10-18 eV |
| Sn-108 | — | 10.30 m | Electron capture / beta-plus decay (100%) | -82,069.95 keV | 8,469.03 keV | 7.38 × 10-19 eV |
| Sn-109 | — | 18.1 m | Electron capture / beta-plus decay (100%) | -82,630.18 keV | 8,470.52 keV | 4.20 × 10-19 eV |
| Sn-110 | — | 4.154 h | Electron capture (100%) | -85,841.99 keV | 8,496.09 keV | 3.05 × 10-20 eV |
| Sn-111 | — | 35.3 m | Electron capture / beta-plus decay (100%) | -85,938.58 keV | 8,493.13 keV | 2.15 × 10-19 eV |
| Sn-113 | — | 115.09 d | Electron capture / beta-plus decay (100%) | -88,328.13 keV | 8,506.81 keV | 4.59 × 10-23 eV |
| Sn-121 | — | 27.03 h | Beta-minus decay (100%) | -89,196.63 keV | 8,485.2 keV | 4.69 × 10-21 eV |
| Sn-123 | — | 129.2 d | Beta-minus decay (100%) | -87,814.68 keV | 8,467.23 keV | 4.09 × 10-23 eV |
| Sn-125 | — | 9.64 d | Beta-minus decay (100%) | -85,893.66 keV | 8,445.53 keV | 5.48 × 10-22 eV |
| Sn-126 | — | 2.18E+5 Y | Beta-minus decay (100%) | -86,015.14 keV | 8,443.52 keV | 6.63 × 10-29 eV |
| Sn-127 | — | 2.10 h | Beta-minus decay (100%) | -83,469.58 keV | 8,420.55 keV | 6.03 × 10-20 eV |
| Sn-128 | — | 59.07 m | Beta-minus decay (100%) | -83,361.43 keV | 8,416.97 keV | 1.29 × 10-19 eV |
| Sn-129 | — | 2.23 m | Beta-minus decay (100%) | -80,590.6 keV | 8,392.82 keV | 3.41 × 10-18 eV |
| Sn-130 | — | 3.72 m | Beta-minus decay (100%) | -80,132.22 keV | 8,386.82 keV | 2.04 × 10-18 eV |
| Sn-131 | — | 56.0 s | Beta-minus decay (100%) | -77,264.58 keV | 8,362.52 keV | 8.15 × 10-18 eV |
| Sn-132 | — | 39.7 s | Beta-minus decay (100%) | -76,546.55 keV | 8,354.87 keV | 1.15 × 10-17 eV |
| Sn-133 | — | 1.46 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.0294%) | -70,873.89 keV | 8,310.09 keV | 3.12 × 10-16 eV |
| Sn-134 | — | 1.050 s | Beta-minus decay (100%), Beta-minus, neutron emission (17%) | -66,433.76 keV | 8,275.17 keV | 4.35 × 10-16 eV |
| Sn-135 | — | 515 ms | Beta-minus decay (100%), Beta-minus, neutron emission (21%), B-2N | -60,632.25 keV | 8,230.69 keV | 8.86 × 10-16 eV |
| Sn-136 | — | 345 ms | Beta-minus decay (100%), Beta-minus, neutron emission (27%) | -56,170 keV | 8,197 keV | 1.32 × 10-15 eV |
| Sn-137 | — | 190 ms | Beta-minus decay (100%), Beta-minus, neutron emission (58%) | -50,150 keV | 8,152 keV | 2.40 × 10-15 eV |
| Sn-138 | — | 140 ms | Beta-minus decay (100%), Beta-minus, neutron emission (36%), B-2N | -45,510 keV | 8,118 keV | 3.26 × 10-15 eV |
| Sn-139 | — | 130 ms | Beta-minus decay (100%), Beta-minus, neutron emission, B-3N | -39,310 keV | 8,073 keV | 3.51 × 10-15 eV |
| Sn-140 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | -34,490 keV | 8,038 keV | — |