43Tc96.90636
Transition metal

Technetium

Technetium holds a unique place on the periodic table: it was the first element ever created artificially rather than found in nature, and every one of its isotopes is radioactive. Despite that, one of its forms has become one of the most important tools in modern medicine.

Group · Period
7 · 5
At room temp
solid
Melts at
2430 K
Density
11 g/cm³
Discovered
1937

Uses

Technetium’s overwhelming real-world importance is in medicine. The isotope technetium-99m emits a form of radiation that’s easy to detect externally, decays away quickly, and can be attached to different carrier molecules that target specific organs or tissues. Injected in small, carefully calculated doses, it’s used in a huge share of nuclear medicine imaging scans worldwide, helping doctors examine bone health, heart function, and other conditions without invasive procedures.

Outside medicine, technetium has essentially no practical use. Because every isotope is radioactive, it’s produced only in the small quantities needed for research and healthcare, and it plays no role in construction, manufacturing or everyday products the way many other transition metals do.

History

Technetium’s existence was actually predicted decades before it was found, since Mendeleev’s periodic table left a gap for an undiscovered element between molybdenum and ruthenium. Several premature discovery claims were made and later disproven, until 1937, when Italian physicists Carlo Perrier and Emilio Segrè examined a sample of molybdenum that had been bombarded with deuterons in Ernest Lawrence’s cyclotron at Berkeley. They identified a new element that hadn’t been extracted from any natural source but had instead been created directly through nuclear reactions. They named it technetium, from the Greek word technetos, meaning artificial, marking it as the first element in history to be made by humans before ever being found in nature.

Fun facts

  • Technetium was the first element to be produced artificially rather than discovered in nature, made in a particle accelerator in 1937.
  • Its name comes from the Greek word 'technetos,' meaning artificial, a direct reference to how it was created.
  • No isotope of technetium is stable — every form of the element is radioactive, which is why it's essentially absent from the natural world.

Frequently asked questions

Does technetium occur naturally on Earth at all?

Only in extraordinarily tiny, fleeting traces, produced when uranium ore spontaneously undergoes fission deep underground. For practical purposes, essentially all the technetium used today is manufactured, which is what makes it so unusual among the elements.

Why isn't technetium used in construction or industry like other metals?

Because it's radioactive, synthetic and expensive to produce, technetium has no meaningful structural or industrial role — it would be both impractical and hazardous to use in bulk. Its value lies almost entirely in the tiny, carefully controlled quantities used for medical purposes.

What is technetium actually used for, then?

Its main real-world application is in medicine, specifically the isotope technetium-99m, which is injected in small, safe amounts as a tracer for diagnostic imaging. Its radiation is detected by a gamma camera to reveal how organs and tissues, such as the heart, bones or kidneys, are functioning.

Compounds

3 notable compounds containing Tc

  • NaTcO4salt

    Sodium pertechnetate

    A water-soluble salt containing technetium-99m that is eluted directly from hospital technetium generators and injected as the workhorse radioactive tracer of nuclear medicine.

    Used for: Most widely used radioactive tracer for diagnostic imaging (thyroid and bone scans)

  • TcO2oxide

    Technetium dioxide

    A dark, insoluble oxide of technetium formed when pertechnetate is reduced, relevant to how technetium behaves in nuclear waste and reactor environments.

    Used for: Studied in nuclear waste chemistry for technetium's environmental behavior

  • Tc2O7oxide

    Technetium heptoxide

    A yellow, volatile solid that is the highest oxide of technetium, formed by burning the metal in oxygen, and dissolves in water to give pertechnetic acid.

    Used for: Laboratory intermediate for preparing other technetium compounds

Isotopes

38 known isotopes

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IsotopeNatural abundanceHalf-lifeDecay modeMass excessBinding energy / nucleonDecay width
Tc-97 4.21E+6 Y Electron capture (100%) -87,224.44 keV 8,623.73 keV 3.43 × 10-30 eV
Tc-98 4.2E+6 Y Beta-minus decay (100%) -86,432.21 keV 8,610 keV 3.44 × 10-30 eV
Tc-99 2.111E+5 Y Beta-minus decay (100%) -87,327.87 keV 8,613.61 keV 6.85 × 10-29 eV
Show all 38 isotopes
Tc-85 100 ns Proton emission -45,850 keV 8,215 keV 4.56 × 10-9 eV
Tc-86 55 ms Electron capture / beta-plus decay (100%), ECP -51,570 keV 8,280 keV 8.30 × 10-15 eV
Tc-87 2.2 s Electron capture / beta-plus decay (100%) -57,690.05 keV 8,347.74 keV 2.07 × 10-16 eV
Tc-88 6.4 s Electron capture / beta-plus decay (100%), ECP -61,670.3 keV 8,389.83 keV 7.13 × 10-17 eV
Tc-89 12.8 s Electron capture / beta-plus decay (100%) -67,394.86 keV 8,450.58 keV 3.56 × 10-17 eV
Tc-90 49.2 s Electron capture (100%) -70,724.7 keV 8,483.36 keV 9.27 × 10-18 eV
Tc-91 3.14 m Electron capture / beta-plus decay (100%) -75,986.66 keV 8,536.66 keV 2.42 × 10-18 eV
Tc-92 4.25 m Electron capture / beta-plus decay (100%) -78,925.7 keV 8,563.54 keV 1.79 × 10-18 eV
Tc-93 2.75 h Electron capture / beta-plus decay (100%) -83,606.12 keV 8,608.58 keV 4.61 × 10-20 eV
Tc-94 293 m Electron capture / beta-plus decay (100%) -84,158.33 keV 8,608.74 keV 2.60 × 10-20 eV
Tc-95 20.0 h Electron capture / beta-plus decay (100%) -86,021.36 keV 8,622.69 keV 6.34 × 10-21 eV
Tc-96 4.28 d Electron capture / beta-plus decay (100%) -85,821.65 keV 8,614.87 keV 1.23 × 10-21 eV
Tc-100 15.65 s Beta-minus decay (99.9974%), Electron capture (0.0026%) -86,020.95 keV 8,595.12 keV 2.92 × 10-17 eV
Tc-101 14.22 m Beta-minus decay (100%) -86,344.59 keV 8,593.14 keV 5.35 × 10-19 eV
Tc-102 5.28 s Beta-minus decay (100%) -84,572.92 keV 8,570.65 keV 8.64 × 10-17 eV
Tc-103 54.2 s Beta-minus decay (100%) -84,603.92 keV 8,566.1 keV 8.42 × 10-18 eV
Tc-104 18.3 m Beta-minus decay (100%) -82,498.97 keV 8,541.11 keV 4.16 × 10-19 eV
Tc-105 7.64 m Beta-minus decay (100%) -82,286.3 keV 8,534.61 keV 9.95 × 10-19 eV
Tc-106 35.6 s Beta-minus decay (100%) -79,776.25 keV 8,506.56 keV 1.28 × 10-17 eV
Tc-107 21.2 s Beta-minus decay (100%) -78,749.97 keV 8,492.9 keV 2.15 × 10-17 eV
Tc-108 5.17 s Beta-minus decay (100%) -75,922.83 keV 8,462.82 keV 8.82 × 10-17 eV
Tc-109 0.91 s Beta-minus decay (100%), Beta-minus, neutron emission (0.08%) -74,282.83 keV 8,444.18 keV 5.01 × 10-16 eV
Tc-110 0.900 s Beta-minus decay (100%), Beta-minus, neutron emission (0.04%) -71,034.56 keV 8,411.26 keV 5.07 × 10-16 eV
Tc-111 290 ms Beta-minus decay (100%), Beta-minus, neutron emission (0.85%) -69,024.68 keV 8,390.09 keV 1.57 × 10-15 eV
Tc-112 271 ms Beta-minus decay (100%), Beta-minus, neutron emission (1.5%) -65,258.93 keV 8,353.62 keV 1.68 × 10-15 eV
Tc-113 152 ms Beta-minus decay (100%), Beta-minus, neutron emission (2.1%) -62,811.55 keV 8,329.47 keV 3.00 × 10-15 eV
Tc-114 100 ms Beta-minus decay (100%), Beta-minus, neutron emission -58,600.29 keV 8,290.26 keV 4.56 × 10-15 eV
Tc-115 78 ms Beta-minus decay (100%), Beta-minus, neutron emission -55,796 keV 8,264 keV 5.85 × 10-15 eV
Tc-116 57 ms Beta-minus decay (100%), B-2N, Beta-minus, neutron emission -51,214 keV 8,223 keV 8.00 × 10-15 eV
Tc-117 44.5 ms Beta-minus decay (100%), Beta-minus, neutron emission, B-2N -48,140 keV 8,195 keV 1.03 × 10-14 eV
Tc-118 30 ms Beta-minus decay (100%), Beta-minus, neutron emission, B-2N -43,290 keV 8,153 keV 1.52 × 10-14 eV
Tc-119 22 ms Beta-minus decay (100%), Beta-minus, neutron emission, B-2N -40,170 keV 8,126 keV 2.07 × 10-14 eV
Tc-120 21 ms Beta-minus decay (100%), B-2N, Beta-minus, neutron emission -35,000 keV 8,083 keV 2.17 × 10-14 eV
Tc-121 22 ms Beta-minus decay (100%), Beta-minus, neutron emission, B-2N -31,540 keV 8,054 keV 2.07 × 10-14 eV
Tc-122 Beta-minus decay (100%), Beta-minus, neutron emission, B-2N -26,305 keV 8,011 keV