Niobium
Niobium is a soft, gray transition metal so chemically similar to tantalum, its neighbor on the periodic table, that the two were confused for decades after niobium's discovery. Today it's prized for a very different property — its ability to become a superconductor at low temperatures.
- Group · Period
- 5 · 5
- At room temp
- solid
- Melts at
- 2750 K
- Density
- 8.57 g/cm³
- Discovered
- 1801
Uses
Niobium’s defining modern application is in superconducting magnets: alloyed with titanium or tin, it becomes superconducting at very low temperatures while remaining practical to manufacture into wire and coils, making it the standard material for the powerful magnets used in MRI scanners and large particle accelerators. A much larger volume of niobium, however, goes into steelmaking, where even small amounts added to steel significantly increase its strength, which is valuable for pipelines, automotive components and structural construction.
Niobium is also popular in jewelry and body piercings, since it’s hypoallergenic and can be anodized to produce a striking range of colors without using any dye, purely through controlled oxide layer thickness on its surface.
History
Niobium was discovered in 1801 by English chemist Charles Hatchett, who found it in a mineral sample sent to London from Connecticut and initially named it columbium. Years later, chemists realized that columbium was extremely difficult to distinguish from tantalum, a similar element discovered around the same time, and for decades many scientists believed the two were actually the same element. The confusion was eventually resolved, and in 1949 the International Union of Pure and Applied Chemistry formally adopted the name niobium, after Niobe, the mythological daughter of Tantalus, extending the family connection between the two closely related elements into their names.
Fun facts
- Niobium is named after Niobe, a figure from Greek mythology and the daughter of Tantalus — a fitting pair, since niobium was long confused with tantalum.
- Niobium-titanium alloy wire is the standard superconducting material used in the powerful magnets inside MRI scanners and particle accelerators.
- For much of the 19th and 20th centuries, the element was known in the United States as columbium, a name some industries used long after niobium became the official one.
Frequently asked questions
Why does niobium have two names — niobium and columbium?
English chemist Charles Hatchett originally named it columbium when he identified it in 1801. Because it's chemically so similar to tantalum, the two elements were confused for years, and different scientific communities ended up using different names. In 1949, the international chemistry body IUPAC officially settled on niobium, though some American industries continued using columbium informally afterward.
Why is niobium important for superconducting magnets?
Niobium alloys, especially niobium-titanium, become superconducting — carrying electric current with zero resistance — when cooled to very low temperatures, while still being practical to draw into wire and wind into coils. That combination makes them the standard choice for the powerful magnets used in MRI machines and particle accelerators.
How is niobium related to tantalum?
The two elements sit directly below one another on the periodic table and share very similar chemical behavior, which is why they occur together in the same ores and were historically hard to tell apart. Their names even echo each other, drawn from Niobe and her father Tantalus in Greek mythology.
Compounds
5 notable compounds containing Nb
- LiNbO3industrial
Lithium niobate
A synthetic crystal with strong piezoelectric and nonlinear-optical properties, grown in large single crystals for use throughout the electronics and photonics industries.
Used for: Surface acoustic wave filters in phones and optical modulators in telecom equipment
- NbCindustrial
Niobium carbide
An extremely hard, high-melting-point ceramic compound often added to tungsten carbide cutting tools to refine their grain structure.
Used for: Grain-refining additive in cemented carbide cutting tools
- NbNindustrial
Niobium nitride
A hard ceramic compound that becomes superconducting at a relatively high temperature for a simple binary compound, making it useful in sensitive detectors.
Used for: Superconducting single-photon detectors and thin-film coatings
- NbCl5halide
Niobium pentachloride
A yellow, moisture-sensitive solid that is the standard entry point into niobium chemistry, readily converted into other niobium compounds.
Used for: Precursor for niobium catalysts and organoniobium compounds
- Nb2O5oxide
Niobium pentoxide
A white, chemically stable oxide and the starting material for nearly all commercial niobium chemicals, valued for its high refractive index.
Used for: High-refractive-index component in camera lens glass and capacitor dielectrics
Isotopes
37 known isotopes
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| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Nb-93 stable | 100% | Stable | — | -87,212.84 keV | 8,664.18 keV | — |
Show all 37 isotopes
| Nb-81 | — | 200 ns | Electron capture / beta-plus decay | -46,360 keV | 8,248 keV | 2.28 × 10-9 eV |
| Nb-82 | — | 50 ms | Electron capture / beta-plus decay (100%), ECP | -51,810 keV | 8,312 keV | 9.12 × 10-15 eV |
| Nb-83 | — | 3.9 s | Electron capture / beta-plus decay (100%) | -57,612.91 keV | 8,378.99 keV | 1.17 × 10-16 eV |
| Nb-84 | — | 9.8 s | Electron capture / beta-plus decay (100%), ECP | -61,193.84 keV | 8,417.96 keV | 4.66 × 10-17 eV |
| Nb-85 | — | 20.5 s | Electron capture / beta-plus decay (100%) | -66,279.68 keV | 8,473.71 keV | 2.23 × 10-17 eV |
| Nb-86 | — | 88 s | Electron capture / beta-plus decay (100%) | -69,134.06 keV | 8,502.22 keV | 5.18 × 10-18 eV |
| Nb-87 | — | 3.7 m | Electron capture / beta-plus decay (100%) | -73,874.49 keV | 8,551.76 keV | 2.06 × 10-18 eV |
| Nb-88 | — | 14.50 m | Electron capture / beta-plus decay (100%) | -76,171.56 keV | 8,572.4 keV | 5.24 × 10-19 eV |
| Nb-89 | — | 2.03 h | Electron capture / beta-plus decay (100%) | -80,625.76 keV | 8,616.82 keV | 6.24 × 10-20 eV |
| Nb-90 | — | 14.60 h | Electron capture / beta-plus decay (100%) | -82,661.53 keV | 8,633.38 keV | 8.68 × 10-21 eV |
| Nb-91 | — | 6.8E+2 Y | Electron capture / beta-plus decay (100%) | -86,638.03 keV | 8,670.9 keV | 2.13 × 10-26 eV |
| Nb-92 | — | 3.47E+7 Y | Electron capture / beta-plus decay (100%) | -86,453.29 keV | 8,662.37 keV | 4.17 × 10-31 eV |
| Nb-94 | — | 2.03E+4 Y | Beta-minus decay (100%) | -86,369.06 keV | 8,648.9 keV | 7.12 × 10-28 eV |
| Nb-95 | — | 34.991 d | Beta-minus decay (100%) | -86,786.27 keV | 8,647.21 keV | 1.51 × 10-22 eV |
| Nb-96 | — | 23.35 h | Beta-minus decay (100%) | -85,602.83 keV | 8,628.89 keV | 5.43 × 10-21 eV |
| Nb-97 | — | 72.1 m | Beta-minus decay (100%) | -85,602.8 keV | 8,623.14 keV | 1.05 × 10-19 eV |
| Nb-98 | — | 2.86 s | Beta-minus decay (100%) | -83,524.61 keV | 8,596.3 keV | 1.60 × 10-16 eV |
| Nb-99 | — | 15.0 s | Beta-minus decay (100%) | -82,335.34 keV | 8,578.99 keV | 3.04 × 10-17 eV |
| Nb-100 | — | 1.4 s | Beta-minus decay (100%) | -79,791.25 keV | 8,548.47 keV | 3.26 × 10-16 eV |
| Nb-101 | — | 7.1 s | Beta-minus decay (100%) | -78,891.49 keV | 8,534.84 keV | 6.43 × 10-17 eV |
| Nb-102 | — | 4.3 s | Beta-minus decay (100%) | -76,298.27 keV | 8,504.87 keV | 1.06 × 10-16 eV |
| Nb-103 | — | 1.5 s | Beta-minus decay (100%) | -75,028.67 keV | 8,488.33 keV | 3.04 × 10-16 eV |
| Nb-104 | — | 4.9 s | Beta-minus decay (100%), Beta-minus, neutron emission (0.06%) | -71,811 keV | 8,453.38 keV | 9.31 × 10-17 eV |
| Nb-105 | — | 2.91 s | Beta-minus decay (100%), Beta-minus, neutron emission (1.7%) | -69,915.55 keV | 8,431.69 keV | 1.57 × 10-16 eV |
| Nb-106 | — | 1.02 s | Beta-minus decay (100%), Beta-minus, neutron emission (4.5%) | -66,202.68 keV | 8,393.27 keV | 4.47 × 10-16 eV |
| Nb-107 | — | 300 ms | Beta-minus decay (100%) | -63,723.81 keV | 8,367.09 keV | 1.52 × 10-15 eV |
| Nb-108 | — | 198 ms | Beta-minus decay (100%), Beta-minus, neutron emission (6.3%), B-2N | -59,545.2 keV | 8,325.66 keV | 2.30 × 10-15 eV |
| Nb-109 | — | 108 ms | Beta-minus decay (100%), Beta-minus, neutron emission (15%) | -56,689.8 keV | 8,297.13 keV | 4.22 × 10-15 eV |
| Nb-110 | — | 82 ms | Beta-minus decay (100%), Beta-minus, neutron emission (40%) | -52,309.91 keV | 8,255.26 keV | 5.56 × 10-15 eV |
| Nb-111 | — | 54 ms | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | -48,960 keV | 8,223 keV | 8.45 × 10-15 eV |
| Nb-112 | — | 33 ms | Beta-minus decay (100%) | -44,070 keV | 8,178 keV | 1.38 × 10-14 eV |
| Nb-113 | — | 32 ms | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | -40,210 keV | 8,143 keV | 1.43 × 10-14 eV |
| Nb-114 | — | 17 ms | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | -34,960 keV | 8,097 keV | 2.68 × 10-14 eV |
| Nb-115 | — | 23 ms | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | -30,880 keV | 8,061 keV | 1.98 × 10-14 eV |
| Nb-116 | — | — | Beta-minus decay (100%), B-3N, B-2N | -25,230 keV | 8,012 keV | — |
| Nb-117 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission, B-2N | — | — | — |