Mercury
Mercury is a heavy, silvery metal that is liquid at room temperature — the only metal with that property — which has made it as fascinating as it is hazardous throughout history. It flows and beads like no other metal, but it's also toxic to the nervous system, and its use has been phased out of most everyday products in recent decades for that reason.
- Group · Period
- 12 · 6
- At room temp
- liquid
- Melts at
- 234.32 K
- Density
- 13.5336 g/cm³
- Discovered
- Ancient
Uses
Mercury’s unusual combination of being liquid, dense, and a good conductor of electricity made it useful in instruments for centuries — traditional thermometers and barometers relied on how precisely and visibly a column of mercury expands and contracts with temperature or pressure. Most of those uses have been phased out over the past few decades because of mercury’s toxicity, replaced by digital sensors or safer liquids. Mercury vapor is still used inside some fluorescent and compact fluorescent light bulbs, where it’s essential to producing the light, though these bulbs require careful disposal for the same reason.
Historically, mercury played a major role in gold and silver mining through a process called amalgamation, where it was used to extract precious metal from ore — a practice that caused serious environmental contamination in many regions and is now restricted or banned in much of the world. Dental amalgam fillings, another traditional use, have also declined sharply as alternative materials have become standard.
History
Mercury has been known since antiquity, with no single discoverer — it appears in the archaeological and written record of ancient Egypt, China, and Greece, sometimes found in tombs and sometimes used, ironically, in early medicines and cosmetics despite its toxicity. Its modern name comes from the fast-moving Roman god Mercury, a nod to how quickly liquid mercury moves and beads when disturbed, while its symbol, Hg, instead reflects its older Latin name, hydrargyrum. Understanding of just how dangerous mercury exposure could be developed gradually, and it was only in the 20th century that its use in everyday products came under serious scientific and regulatory scrutiny.
Fun facts
- Mercury freezes solid at about −38.83°C, an unusually low melting point that's why it stays liquid at normal room temperature.
- Its chemical symbol, Hg, comes from the Latin hydrargyrum, meaning 'liquid silver.'
- Mercury is dense enough that a solid iron bar can actually float on top of a pool of it.
Frequently asked questions
Why is mercury liquid at room temperature when almost no other metal is?
Mercury's electrons are held unusually tightly by its nucleus, a relativistic effect that weakens the metallic bonding between mercury atoms compared to most metals. That weaker bonding lowers its melting point dramatically, to below room temperature, while nearly every other metal stays solid until it's heated far hotter.
Why did mercury thermometers get phased out?
Mercury is toxic, especially as vapor, which is easily released if a thermometer or older instrument breaks. Digital and alcohol-based thermometers work just as well without that risk, so most countries have restricted or banned mercury thermometers and similar consumer devices in favor of safer alternatives.
Is it dangerous to touch liquid mercury?
Brief, occasional skin contact with liquid mercury is far less dangerous than breathing its vapor, which mercury releases slowly even at room temperature and which can build up in enclosed spaces. The bigger health risks come from repeated exposure or from mercury compounds that can build up in the body over time, which is why spills are treated seriously rather than wiped up casually.
Compounds
5 notable compounds containing Hg
- Hg2Cl2salt
Mercury(I) chloride
Known as calomel, a nearly insoluble white solid built around a metal-metal bonded Hg2²⁺ ion rather than separate Hg⁺ centers, which is unusual for a group 12 element.
Used for: Reference electrode component in electrochemistry (calomel electrode)
- HgCl2salt
Mercury(II) chloride
A white crystalline solid once known as corrosive sublimate, notable for dissolving as largely undissociated molecules rather than free ions despite being an ionic-looking salt.
Used for: Historic wood preservative and disinfectant, now largely discontinued for its toxicity
- HgI2salt
Mercury(II) iodide
A bright scarlet solid that reversibly turns yellow above about 127°C as its crystal structure shifts, then reverts to red on cooling or when touched.
Used for: Room-temperature radiation detector material and component of Nessler's reagent
- HgOoxide
Mercury(II) oxide
A dense red or yellow solid depending on particle size, formed by heating mercury in air or by precipitation, and one of the few oxides that decomposes back into its elements on strong heating.
Used for: Electrode material in older mercury button-cell batteries
- HgSmineral
Mercury(II) sulfide
The natural mineral cinnabar, occurring as bright red hexagonal crystals and as a black cubic form; it is the chief ore from which metallic mercury has been extracted for thousands of years.
Used for: Historic red pigment (vermilion) and primary mercury ore
Isotopes
47 known isotopes
Swipe to see all columns →
| Isotope | Natural abundance | Half-life | Decay mode | Mass excess | Binding energy / nucleon | Decay width |
|---|---|---|---|---|---|---|
| Hg-196 stable | 0.15% | Stable | — | -31,825.94 keV | 7,914.37 keV | — |
| Hg-198 stable | 10.04% | Stable | — | -30,954.32 keV | 7,911.55 keV | — |
| Hg-199 stable | 16.94% | Stable | — | -29,546.07 keV | 7,905.28 keV | — |
| Hg-200 stable | 23.14% | Stable | — | -29,503.27 keV | 7,905.9 keV | — |
| Hg-201 stable | 13.17% | Stable | — | -27,662.53 keV | 7,897.56 keV | — |
| Hg-202 stable | 29.74% | Stable | — | -27,345.31 keV | 7,896.85 keV | — |
| Hg-204 stable | 6.82% | Stable | — | -24,690.15 keV | 7,885.55 keV | — |
Show all 47 isotopes
| Hg-170 | — | 0.08 ms | Alpha decay (100%) | 5,415 keV | 7,671 keV | 5.70 × 10-12 eV |
| Hg-171 | — | 59 us | Alpha decay (100%) | 3,339 keV | 7,686 keV | 7.73 × 10-12 eV |
| Hg-172 | — | 231 us | Alpha decay (100%) | -1,061.36 keV | 7,713.61 keV | 1.98 × 10-12 eV |
| Hg-173 | — | 0.80 ms | Alpha decay (100%) | -2,661 keV | 7,725 keV | 5.70 × 10-13 eV |
| Hg-174 | — | 2.1 ms | Alpha decay (99.6%) | -6,641.02 keV | 7,749.79 keV | 2.17 × 10-13 eV |
| Hg-175 | — | 10.6 ms | Alpha decay (100%) | -7,969.44 keV | 7,759.21 keV | 4.30 × 10-14 eV |
| Hg-176 | — | 20.3 ms | Alpha decay (94%) | -11,784.64 keV | 7,782.66 keV | 2.25 × 10-14 eV |
| Hg-177 | — | 117 ms | Alpha decay (100%) | -12,775.82 keV | 7,789.89 keV | 3.90 × 10-15 eV |
| Hg-178 | — | 266.5 ms | Alpha decay (70%), Electron capture / beta-plus decay (30%) | -16,315.35 keV | 7,811.36 keV | 1.71 × 10-15 eV |
| Hg-179 | — | 1.05 s | Alpha decay (55%), Electron capture / beta-plus decay (45%), ECP (0.15%) | -16,932.92 keV | 7,816.26 keV | 4.35 × 10-16 eV |
| Hg-180 | — | 2.59 s | Electron capture / beta-plus decay (52%), Alpha decay (48%) | -20,250.51 keV | 7,836.11 keV | 1.76 × 10-16 eV |
| Hg-181 | — | 3.6 s | Electron capture / beta-plus decay (73%), Alpha decay (27%), ECP (0.013%) | -20,661.13 keV | 7,839.68 keV | 1.27 × 10-16 eV |
| Hg-182 | — | 10.83 s | Electron capture / beta-plus decay (86.2%), Alpha decay (13.8%) | -23,576.89 keV | 7,856.97 keV | 4.21 × 10-17 eV |
| Hg-183 | — | 9.4 s | Electron capture / beta-plus decay (88.3%), Alpha decay (11.7%), ECP (0.00026%) | -23,804.66 keV | 7,859.39 keV | 4.85 × 10-17 eV |
| Hg-184 | — | 30.87 s | Electron capture / beta-plus decay (98.89%), Alpha decay (1.11%) | -26,344.79 keV | 7,874.35 keV | 1.48 × 10-17 eV |
| Hg-185 | — | 49.1 s | Electron capture / beta-plus decay (94%), Alpha decay (6%) | -26,183.65 keV | 7,874.54 keV | 9.29 × 10-18 eV |
| Hg-186 | — | 1.38 m | Electron capture / beta-plus decay (99.984%), Alpha decay (0.016%) | -28,539.06 keV | 7,888.26 keV | 5.51 × 10-18 eV |
| Hg-187 | — | 1.9 m | Electron capture / beta-plus decay (100%), Alpha decay (0.00037%) | -28,118.51 keV | 7,886.99 keV | 4.00 × 10-18 eV |
| Hg-188 | — | 3.25 m | Electron capture / beta-plus decay (99.999963%), Alpha decay (0.000037%) | -30,198.35 keV | 7,899.03 keV | 2.34 × 10-18 eV |
| Hg-189 | — | 7.6 m | Electron capture / beta-plus decay (100%), Alpha decay (0.00003%) | -29,626.38 keV | 7,896.92 keV | 1.00 × 10-18 eV |
| Hg-190 | — | 20.0 m | Electron capture / beta-plus decay (100%), Alpha decay (3.4e-7%) | -31,370.63 keV | 7,907.02 keV | 3.80 × 10-19 eV |
| Hg-191 | — | 49 m | Electron capture / beta-plus decay (100%) | -30,591.85 keV | 7,903.8 keV | 1.55 × 10-19 eV |
| Hg-192 | — | 4.85 h | Electron capture (100%) | -32,011.48 keV | 7,912.07 keV | 2.61 × 10-20 eV |
| Hg-193 | — | 3.80 h | Electron capture / beta-plus decay (100%) | -31,062.17 keV | 7,907.97 keV | 3.34 × 10-20 eV |
| Hg-194 | — | 447 Y | Electron capture (100%) | -32,183.95 keV | 7,914.6 keV | 3.23 × 10-26 eV |
| Hg-195 | — | 10.53 h | Electron capture / beta-plus decay (100%) | -31,013.34 keV | 7,909.4 keV | 1.20 × 10-20 eV |
| Hg-197 | — | 64.14 h | Electron capture (100%) | -30,540.23 keV | 7,908.64 keV | 1.98 × 10-21 eV |
| Hg-203 | — | 46.610 d | Beta-minus decay (100%) | -25,269.2 keV | 7,887.48 keV | 1.13 × 10-22 eV |
| Hg-205 | — | 5.14 m | Beta-minus decay (100%) | -22,287.72 keV | 7,874.73 keV | 1.48 × 10-18 eV |
| Hg-206 | — | 8.32 m | Beta-minus decay (100%) | -20,945.73 keV | 7,869.17 keV | 9.14 × 10-19 eV |
| Hg-207 | — | 2.9 m | Beta-minus decay (100%) | -16,487.45 keV | 7,848.61 keV | 2.62 × 10-18 eV |
| Hg-208 | — | 41 m | Beta-minus decay (100%) | -13,265.41 keV | 7,834.19 keV | 1.85 × 10-19 eV |
| Hg-209 | — | 36 s | Beta-minus decay (100%) | -8,610 keV | 7,813 keV | 1.27 × 10-17 eV |
| Hg-210 | — | — | Unknown | -5,300 keV | 7,799 keV | — |
| Hg-211 | — | 300 ns | Beta-minus decay, Beta-minus, neutron emission | -390 keV | 7,777 keV | 1.52 × 10-9 eV |
| Hg-212 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission | 3,020 keV | 7,762 keV | — |
| Hg-213 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission | 8,200 keV | 7,739 keV | — |
| Hg-214 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission | 11,770 keV | 7,724 keV | — |
| Hg-215 | — | — | Beta-minus decay (100%), Beta-minus, neutron emission | 17,110 keV | 7,701 keV | — |
| Hg-216 | — | 300 ns | Beta-minus decay, Beta-minus, neutron emission | 20,920 keV | 7,685 keV | 1.52 × 10-9 eV |